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Electrochemical, Spectroscopic, and Quantum Chemical Study of Electrocatalytic Hydrogen Evolution in the Presence of N-Methyl-9-phenylacridinium Iodide

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Abstract

Main intermediates in the electrocatalytic hydrogen evolution promoted by N-methyl-9-phenyl-acridinium iodide have been identified and characterized using cyclic voltammetry (CV) and NMR and ESR spectroscopy. A probable mechanism of the process has been proposed on the basis of DFT quantum chemical calculations. Analysis of structural and energetic parameters of intermediate products has shown that the electrocatalytic process involves formation of N-protonated radical cation, followed by reductive elimination of molecular hydrogen in the bimolecular reaction of two radical cations.

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Acknowledgments

The authors thank Prof. V.V. Novikov for recording the ESR and NMR spectra.

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Authors and Affiliations

  1. Ogarev Mordovian National Research State University, Saransk, Russia

    A. V. Dolganov, O. V. Tarasova, A. V. Balandina, O. Yu. Chernyaeva, V. Yu. Yurova, Yu. M. Selivanova & A. D. Yudina

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  1. A. V. Dolganov
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  2. O. V. Tarasova
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  3. A. V. Balandina
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  4. O. Yu. Chernyaeva
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  5. V. Yu. Yurova
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  6. Yu. M. Selivanova
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  7. A. D. Yudina
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Corresponding author

Correspondence to A. V. Dolganov.

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No conflict of interests is declared by the authors.

Russian Text © The Author(s), 2019, published in Zhurnal Organicheskoi Khimii, 2019, Vol. 55, No. 7, pp. 1030–1037.

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Dolganov, A.V., Tarasova, O.V., Balandina, A.V. et al. Electrochemical, Spectroscopic, and Quantum Chemical Study of Electrocatalytic Hydrogen Evolution in the Presence of N-Methyl-9-phenylacridinium Iodide. Russ J Org Chem 55, 938–943 (2019). https://doi.org/10.1134/S1070428019070030

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  • DOI: https://doi.org/10.1134/S1070428019070030

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