Abstract
Poly(1,2-phenylenedithiocarbamate) (PPDTC) was prepared by the reaction of 2-aminothiophenol with carbon disulfide followed by condensation through the removal of H2S gas. PPDTC was used as a ligand to prepare four poly(1,2-phenylenedithiocarbamate)–metal complexes of iron(II), cobalt(II), copper(II), and lead(II), by refluxing with the metal salts. The polymer and its metal complexes were investigated by elemental analyses, UV–visible and IR spectroscopy, inherent viscosity, and magnetic susceptibility. The DC electrical conductivity variation with the temperature in the range 298–498 K of PPDTC and its polymeric copper complex was measured. Both polymer and polymer metal complexes showed an increase in electrical conductivity with an increase in temperature: typical semiconductor behavior. The proposed structure of the complexes is (MLX2·mH2O) n .
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
C. S. Marvel and N. Torkoy, J. Am. Chem. Soc. 79, 6000 (1957).
M. Patel and S. H. Patil, Synth. React. Inorg. Met.-Org. Chem. 13, 133 (1983).
J. E. Katon (ed.), Organic Semiconducting Polymers (Marcel Dekker, New York, 1968).
R. Riedere and W. Sawodny, Ang. Chem. 16, 859 (1977).
J. Hodghkin, Encyclopedia of Polymer Science and Engineering, 2nd ed. (John Wiley, New York, 1985), Vol. III, p. 363.
A. El-Shekeil, F. Al-Fusufy, and S. Saknidy, Polym. Int. 42, 39 (1997).
A. El-Shekeil, S. D. Hamid, and D. A. Ali, Polym. Bull. 39, 1 (1997).
R. M. Silverstein, G. C. Bassler, and T. C. Morrill, Spectrometric Identification of Organic Compounds, 4th ed. (John Wiley, New York, 1981).
A. El-Shekeil and A. El-Sonbati, TMC 17, 20 (1992).
B. N. Figgis and J. Lewis, Prog. Inorg. Chem. 6, 176 (1964).
G. R. Burns, Inorg. Chem. 7, 277 (1967).
A. El-Shekeil, H. Al-Maydama, and A. Al-Karbooly, J. Inorg. Organomet. Polym. 7, 121 (1997).
A. El-Shekeil and A. Sonbati, Ang. Makromol. Chem. 59, 319 (1992).
K. Mukkanti, K. B. Pandeys, and R. P. Singh, Ind. J. Chem. 21A, 641 (1982).
F. Cotton and G. Wilkinson, Advanced Inorganic Chemistry, 3rd ed. (John Wiley, New York, 1972), p. 862.
D. K. Rastogi and K. C. Sharma, J. Inorg. Nucl. Chem. 36, 2219 (1974).
F. A. Cotton and J. J. Wise, Inorg. Chem. 6, 917 (1976).
W. E. Hatfield and T. S. Piper, Inorg. Chem. 3, 841 (1964).
A. Al-Dujaili, R. Shalash, and T. Yasagh, Eur. Polym. J. 29, 947 (1990).
A. El-Shekeil, H. Al-Maydama, A. Al-Karbooly, and M. Khalid, Polymer 40, 2879 (1998).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
El-Shekeil, A., Al-Maydama, H. & Al-Karbooly, A. Synthesis and Characterization of Some Poly(1,2-Phenylenedithiocarbamate)–Metal Complexes. Journal of Inorganic and Organometallic Polymers 8, 167–178 (1998). https://doi.org/10.1023/A:1021630204888
Issue Date:
DOI: https://doi.org/10.1023/A:1021630204888