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Electrochemical Synthesis of Polymer Complexes with Selected Metals Based on 1-Vinyl-1,2,4-triazole

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Abstract

A single-stage electrochemical synthesis of polymer complexes of Fe, Co, Ni, and Cu based on 1-vinyl-1,2,4-triazole has been elaborated. It has been found that 1-vinyl-1,2,4-triazole can be electropolymerized via the double bonds opening in the presence of potassium persulfate. At low current density, colored metal-polymer coatings have been formed at the surface of electrodes, and powders have been obtained at high current density. The composition and structure of the polymeric complexes have been elucidated by means of infrared spectroscopy, gas-liquid chromatography, elemental analysis, and thermogravimetric analysis.

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Authors and Affiliations

  1. National Polytechnic University of Armenia, 0009, Yerevan, Armenia

    S. H. Sargsyan, I. G. Agadjanyan & K. M. Khizantsyan

  2. Yerevan State Medical University after M. Heratsi, 0025, Yerevan, Armenia

    T. S. Sargsyan, A. S. Sargsyan & K. S. Margaryan

Authors
  1. S. H. Sargsyan
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  2. T. S. Sargsyan
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  3. I. G. Agadjanyan
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  4. K. M. Khizantsyan
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  5. A. S. Sargsyan
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  6. K. S. Margaryan
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Correspondence to A. S. Sargsyan.

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Translated from Zhurnal Obshchei Khimii, 2021, Vol. 91, No. 2, pp. 269–273 https://doi.org/10.31857/S0044460X21020104.

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Sargsyan, S.H., Sargsyan, T.S., Agadjanyan, I.G. et al. Electrochemical Synthesis of Polymer Complexes with Selected Metals Based on 1-Vinyl-1,2,4-triazole. Russ J Gen Chem 91, 223–226 (2021). https://doi.org/10.1134/S1070363221020109

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  • DOI: https://doi.org/10.1134/S1070363221020109

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