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Non-isothermal crystallization kinetics of V2O5-MoO3-Bi2O3 glasses

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Abstract

Characteristic temperatures, such as T g (glass transition), T x (crystallization temperature) and T l (liquidus temperature) of glasses from the V2O5-MoO3-Bi2O3 system were determined by means of differential thermal analysis (DTA). The higher content of MoO3 improved the thermal stability of the glasses as well as the glass forming ability. The non-isothermal crystallization was investigated and following energies of the crystal growth were obtained: glass #1 (80V2O5·20Bi2O3) E G=280 kJ mol-1, glass #2 (40V2O5·30MoO3·30Bi2O3) E G=422 kJ mol-1 and glass #3 (80MoO3·10V2O5·10Bi2O3) E G=305 kJ mol-1. The crystallization mechanism of glass #1 (n=3) is bulk, of glass #3 (n=1) is surface. Bulk and surface crystallization was supposed in glass #2. The presence of high content of a vanadium oxide acts as a nucleation agent and facilitates bulk crystallization.

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Authors and Affiliations

  1. Insitute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, blvd. "Acad. G. Bonchev" 11, Sofia, 1113, Bulgaria

    R. Iordanova, I. Uzunov & D. Klissurski

  2. Central Laboratory for Electrochemical Power Sources - BAS, Sofia, 1113, Bulgaria

    E. Lefterova

  3. University of Chemical Technology and Metallurgy, Sofia, 1756, Bulgaria

    Y. Dimitriev

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  1. R. Iordanova
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  2. E. Lefterova
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  3. I. Uzunov
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  4. Y. Dimitriev
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  5. D. Klissurski
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Iordanova, R., Lefterova, E., Uzunov, I. et al. Non-isothermal crystallization kinetics of V2O5-MoO3-Bi2O3 glasses. Journal of Thermal Analysis and Calorimetry 70, 393–404 (2002). https://doi.org/10.1023/A:1021612204744

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