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Synthesis and crystal structure of Bi(mpo)3 (Hmpo = 2-mercaptopyridine N-oxide)

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Abstract

The synthesis as well as crystal and molecular structure of [Bi(C5H4NOS)3] are reported. The complex crystallizes in the monoclinic system, space group P21/n with lattice parameters a = 9.6521(3) Å, b = 10.0659(4) Å, c = 18.4484(7) Å, β = 102.13(6)°, and D calc = 2.227 Mg · m−3 for Z = 4. It is clear from the packing diagram that the title compound is a dimer via the secondary coordination. Surrounding Bi atom, three five-membered ring planes (Bi,O,N,C,S) make a dihedral angle of 55.91, 54.72, and 26.13° respectively. The whole crystal presents a three-dimensional network structure as each molecule produces four weak C–H ⋅ ⋅ ⋅ O hydrogen bonds and a weak C–H ⋅ ⋅ ⋅ S hydrogen bond.

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Authors and Affiliations

  1. Department of Chemistry, Xuzhou Normal University, Xuzhou, 221009, People's Republic of China

    De-Zhong Niu, Lai-Long Mu & Shou-Zheng Yu

  2. Chinese Academy of Sciences, Fujian Institute of Research on The Structure of Matter, Fuzhou, 350002, People's Republic of China

    Jiu-Tong Chen

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  1. De-Zhong Niu
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  2. Lai-Long Mu
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  3. Shou-Zheng Yu
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  4. Jiu-Tong Chen
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Correspondence to De-Zhong Niu.

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Niu, DZ., Mu, LL., Yu, SZ. et al. Synthesis and crystal structure of Bi(mpo)3 (Hmpo = 2-mercaptopyridine N-oxide). Journal of Chemical Crystallography 33, 27–31 (2003). https://doi.org/10.1023/A:1021395615863

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