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Neodymium Cyclohexaphosphates in the NdCl3–Li6P6O18–H2O System

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Abstract

The NdCl3–Li6P6O18–H2O system is studied at 20°C, NdCl3 concentrations of 0.05 to 0.1 mol/l, and Li6P6O18 concentrations of 0.025 to 0.15 mol/l. Simple cyclohexaphosphates with the general formula Nd2P6O18 · mH2O (m = 6, 8, 12) are identified, and the double cyclohexaphosphate Li3Nd3(P6O18)2 · 26H2O is obtained for the first time. Li3Nd3(P6O18)2 · 26H2O has a monoclinic structure with unit-cell parameters a = 24.24 Å, b= 9.24 Å, c = 14.53 Å, and β = 125.24°.

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  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991, Russia

    N. N. Chudinova, L. A. Borodina & E. V. Murashova

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  1. N. N. Chudinova
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  2. L. A. Borodina
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  3. E. V. Murashova
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Chudinova, N.N., Borodina, L.A. & Murashova, E.V. Neodymium Cyclohexaphosphates in the NdCl3–Li6P6O18–H2O System. Inorganic Materials 38, 1297–1301 (2002). https://doi.org/10.1023/A:1021387808037

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