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(Arene)ruthenium complexes with the monoanionic carborane ligand [9-SMe2-7,8-C2B9H10]–

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Abstract

The ruthenium arene complexes [(η-arene)Ru(η-9-SMe2-7,8-C2B9H10)]+ (arene = C6H6 (3a); arene = 1,3,5-C6H3Me3 (3b)) with the monoanionic carborane ligand were synthesized by the reactions of the [9-SMe2-7,8-C2B9H10]– anion with [(η-arene)RuCl2]2. The structure of the compound [3a]BPh4 was established by single-crystal X-ray diffraction analysis.

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Authors and Affiliations

  1. Russian Academy of Sciences, A. N. Nesmeyanov Institute of Organoelement Compounds, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    A. R. Kudinov, D. S. Perekalin, P. V. Petrovskii & G. V. Grintselev-Knyazev

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  1. A. R. Kudinov
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  2. D. S. Perekalin
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  3. P. V. Petrovskii
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  4. G. V. Grintselev-Knyazev
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Kudinov, A.R., Perekalin, D.S., Petrovskii, P.V. et al. (Arene)ruthenium complexes with the monoanionic carborane ligand [9-SMe2-7,8-C2B9H10]–. Russian Chemical Bulletin 51, 1928–1930 (2002). https://doi.org/10.1023/A:1021373106780

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