Abstract
The crystal structure of Mo2.0 – x Ni1.0 + x P (x= 0.2) is determined by powder x-ray diffraction (monoclinic symmetry, new structure type, sp. gr. Im, a = 1.04036(5) nm, b= 0.84055(4) nm, c= 0.47357(2) nm, β = 91.538(3)°; R int = 0.094, R prof = 0.197). The 850°C section of the Mo–Ni–P phase diagram is studied in detail, and the crystal-chemical features of molybdenum nickel phosphides are discussed.
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Oryshchyn, S.V., Zhak, O.V., Guérin, P. et al. Structure of Mo2.0 – x Ni1.0 + x P (x = 0.2) and Some Crystal-Chemical Features of Ternary Phases in the Mo–Ni–P System. Inorganic Materials 38, 1195–1202 (2002). https://doi.org/10.1023/A:1021322000768
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DOI: https://doi.org/10.1023/A:1021322000768