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An Xps Study of Solid Solutions Mo1–XNbxS2 (0 < x < 0.15)

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Abstract

Solid solutions Mo1–xNbxS2 (x = 0, 0.05, 0.10, and 0.15) crystallizing in the hexagonal structure 2H-MoS2 are synthesized. The samples are characterized by powder X-ray diffraction (XRD) and Raman spectroscopies, X-ray photoelectron spectroscopy (XPS), and quantum chemical calculations (DFT). The changes occurring in the electronic properties of high-resistivity semiconductor MoS2 and indicating metallic behavior of obtained solid solutions Mo1–xNbxS2 are not accompanied by substantial changes in the atomic photoelectron spectra.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. Yu. Ledneva, S. A. Dalmatova, A. D. Fedorenko, I. P. Asanov, L. N. Mazalov & V. E. Fedorov

  2. Novosibirsk State University, Novosibirsk, Russia

    S. A. Dalmatova, I. P. Asanov, L. N. Mazalov & V. E. Fedorov

  3. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Ekaterinburg, Russia

    A. N. Enyashin

Authors
  1. A. Yu. Ledneva
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  2. S. A. Dalmatova
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  3. A. D. Fedorenko
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  4. I. P. Asanov
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  5. A. N. Enyashin
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  6. L. N. Mazalov
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  7. V. E. Fedorov
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Correspondence to V. E. Fedorov.

Additional information

Original Russian Text © 2018 A. Yu. Ledneva, S. A. Dalmatova, A. D. Fedorenko, I. P. Asanov, A. N. Enyashin, L. N. Mazalov, V. E. Fedorov.

Translated from Zhurnal Strukturnoi Khimii, Vol. 59, No. 8, pp. 1896–1903, November-December, 2018.

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Ledneva, A.Y., Dalmatova, S.A., Fedorenko, A.D. et al. An Xps Study of Solid Solutions Mo1–XNbxS2 (0 < x < 0.15). J Struct Chem 59, 1833–1840 (2018). https://doi.org/10.1134/S0022476618080115

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  • DOI: https://doi.org/10.1134/S0022476618080115

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