Abstract
Single-walled and thin multiwalled carbon nanotubes are prepared by a catalytic-chemical-vapor-deposition method involving the simultaneous formation of Fe or Co nanometric particles from oxide solid solutions based on Al2O3, MgAl2O4 or MgO. This paper is an overview of the authors' work on the characterization by Mössbauer spectroscopy used in complement to electron microscopy and specific-surface-area measurements. It is notably attempted to correlate the nature of the different iron phases in the carbon nanotube-metal-oxide powders with the formation mechanisms of the nanotubes. Massive composites and hydrogen storage are proposed as possible applications.
Similar content being viewed by others
References
Iijima, S., Nature 354 (1991), 56.
Peigney, A., Laurent, Ch., Dobigeon, F. and Rousset, A., J. Mater. Res. 12 (1997), 613.
Flahaut, E., Govindaraj, A., Peigney, A., Laurent, Ch., Rousset, A. and Rao, C. N. R., Chem.Phys. Lett. 300 (1999), 236.
Flahaut, E., Peigney, A., Laurent, Ch. and Rousset, A., J. Mater. Chem. 10 (2000), 249.
Peigney, A., Laurent, Ch., Flahaut, E., Bacsa, R. R. and Rousset, A., Carbon 39 (2001), 507.
Coquay, P., De Grave, E., Vandenberghe, R. E., Dauwe, C., Flahaut, E., Laurent, Ch., Peigney, A. and Rousset, A., Acta Mater. 48 (2000), 3015.
Kingsley, J. J. and Patil, K. C., Mater. Lett. 6 (1988), 427.
Devaux, X., Laurent, Ch. and Rousset, A., NanoStruct. Mater. 2 (1993), 339.
Weiss, R. J., Proc. Phys. Soc. 82 (1963), 281.
Coquay, P., Laurent, Ch., Peigney, A., Quénard, O., De Grave, E. and Vandenberghe, R. E., Hyp. Interact. 130 (2000), 275.
Laurent, Ch., Peigney, A., Dumortier, O. and Rousset, A., J. Eur. Ceram. Soc. 18 (1998), 2005.
Flahaut, E., Peigney, A., Laurent, Ch., Marlière, Ch., Chastel, F. and Rousset, A., Acta Mater. 48 (2000), 3803.
Dillon, A. C., Jones, K. M., Bekkadahl, T. A., Kiang, C. H., Bethune, D. S. and Heben, M. J., Nature 386 (1997), 377.
Bacsa, R. R., Laurent, Ch., Peigney, A., Bacsa, W. S., Vaugien, Th. and Rousset, A., Chem.tiPhys. Lett. 323 (2000), 566.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Coquay, P., De Grave, E., Vandenberghe, R.E. et al. Mössbauer Spectroscopy Involved in the Study of the Catalytic Growth of Carbon Nanotubes. Hyperfine Interactions 139, 289–296 (2002). https://doi.org/10.1023/A:1021239809363
Issue Date:
DOI: https://doi.org/10.1023/A:1021239809363