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Synthesis and crystal structure of Schiff base transition metal complex [Co(PMBP-smdtc)2]⋅2H2O

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Abstract

A cobalt(II) complex, [Co(PMBP-smdtc)2]⋅2H2O, in which PMBP-smdtc is the l-phenyl-3-methyl-4-benzoyl-5-pyrazolone Schiff base of S-methyldithiocarbazate, has been synthesized and characterized by IR spectrum and single crystal X-ray diffraction. The crystal is monoclinic: space group C2/c, with a = 12.455(2) Å, b = 16.024(2) Å, c = 20.513(3) Å, β = 101.18(1)°, V = 4016.3(10) Å3, and Z = 4. The cobalt ion is octahedrally coordinated by two tridentate Schiff base ligands with ONS donor atoms. The molecules are bridged together by two water molecules through H-bond along b axis and one-dimensional indented chain structure is formed.

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Authors and Affiliations

  1. Institute of Applied Chemistry, Xinjiang University, Urumqi, 830046, People's Republic of China

    Yali Ji, Lang Liu, Dianzeng Jia & YongMin Qiao

  2. People's Republic of Chengdu Institute of Organic Chemistry, Chinese Academy of Sciences, Chengdu, 610012, People's Republic of China

    Kaibei Yu

Authors
  1. Yali Ji
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  2. Lang Liu
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  3. Dianzeng Jia
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  4. YongMin Qiao
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  5. Kaibei Yu
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Ji, Y., Liu, L., Jia, D. et al. Synthesis and crystal structure of Schiff base transition metal complex [Co(PMBP-smdtc)2]⋅2H2O. Journal of Chemical Crystallography 32, 505–509 (2002). https://doi.org/10.1023/A:1021105128641

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