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Bis-(thio)ethers as Chelating Ligands for the Pd-Catalyzed Alternating CO/tert-Butylstyrene Copolymerization

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Abstract

We synthesized and characterized new neutral and cationic palladium(II) complexes containing bis-(thio)ether ligands. The cationic compounds catalyzed the alternating CO/tert-butylstyrene copolymerization leading to polyketones with different degrees of stereoregularity depending on the nature of the S-S ligand.

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References

  1. A. Sen, Acc. Chem. Res. 26 (1993) 303.

    Google Scholar 

  2. E. Drent and P.H.M. Budzelaar, Chem. Rev. 96 (1996) 663.

    Google Scholar 

  3. K. Nozaki and T. Hiyama, J. Organomet. Chem. 576 (1999) 248.

    Google Scholar 

  4. For new catalytic systems see: (a) F.J. Parlevliet, M.Z. Zuideveld, C. Kiener, H. Kooijman, A.L. Spek, P.C.J. Kamer and P.W.N.M. van Leeuwen, Organometallics 18 (1999) 3394; (b) J. Schwarz, E. Herdtweck and W.A. Herrmann, Organometallics 10 (2000) 3154; (c) C. Gambs, S. Chaloupka, G. Consiglio and A. Togni, Angew. Chem. Int. Ed. 39 (2000) 2486; (d) C. Bianchini, H.M. Lee, A. Meli, W. Oberhauser, F. Vizza, P. Brüggeller, R. Haid and C. Langes, Chem. Comm. (2000) 777; (e) J.C. Yuan and S.J. Lu, Organometallics 20 (2001) 2697; (f) C.R. Baar, M.C. Jennings and R.J. Puddephatt, Organometallics 20 (2001) 3459. For mechanistic studies see: (g) F.C. Rix, M. Brookhart and P.S. White, J. Am. Chem. Soc. 118 (1996) 4746; (h) M.A. Zuideveld, P.C.J. Kamer, P.W.N.M. van Leeuwen, P.A.A. Klusener, H.A. Stil and C.F. Roobeek, J. Am. Chem. Soc. 120 (1998) 7977; (i) B. Milani, G. Corso, G. Mestroni, C. Carfagna, M. Formica, R. Seraglia, Organometallics 19 (2000) 3435; (j) G.K. Barlow, J.D. Boyle, N.A. Cooley, T. Ghaffar and D.F. Waas, Organometallics 19 (2000) 1470; (k) C.S. Shultz, J. Ledford, J.M. DeSimone and M. Brookhart, J. Am. Chem. Soc. 122 (2000) 6351; (l) K. Nozaki, H. Komaki, Y. Kawashima, T. Hiyama and T. Matsubara, J. Am. Chem. Soc. 123 (2001) 534; (m) W.P. Mul, E. Drent, P.J. Jansens, A.H. Kramer and M.H.W. Sonnemans, J. Am. Chem. Soc. 123 (2001) 5350.

    Google Scholar 

  5. M. Brookhart, M.I. Wagner, G.G.A. Balavoine and H.A. Haddou, J. Am. Chem. Soc. 116 (1994) 3641; (b) B. Milani and G. Mestroni, Comments Inorg. Chem. 20 (1999) 301; (c) M.T. Reetz, G. Haderlein and K. Angermund, J. Am. Chem. Soc. 122 (2000) 996; (d) A. Bastero, A. Ruiz, J.A. Reina, C. Claver, A.M. Guerrero, F.A. Jalón and B.R. Manzano, J. Organomet. Chem. 619 (2001) 287; (e) C. Carfagna, G. Gatti, D. Martini and C. Pettinari, Organometallics 20 (2001) 2175; (f) A. Bastero, S. Castillón, C. Claver and A. Ruiz, Eur. J. Inorg. Chem. 12 (2001) 3009.

    Google Scholar 

  6. A. Aeby and G. Consiglio, Inorg. Chim. Acta 296 (2000) 45.

    Google Scholar 

  7. J.C. Yuan and S.J. Lu, J. Polym. Sci. A: Polym. Chem. 38 (2000) 2919.

    Google Scholar 

  8. J.A. Van Doorn and E. Drent, Eur. Pat. Appl. 345 847 (1989), Chem. Abst. 112 (1990) 199339.

  9. G.P. Suranna, P. Mastrorilli, C.F. Nobile and W. Keim, Inorg. Chim. Acta 305 (2000) 151.

    Google Scholar 

  10. M. Diéguez, A. Orejón, A.M. Masdeu-Bultó, R. Echarri, S. Castillón, C. Claver and A. Ruiz, J. Chem. Soc., Dalton Trans. (1997) 4611; (b) M. Diéguez, A. Ruiz, C. Claver, M.M. Pereira and A.M. d'A Rocha Gonsalves, J. Chem. Soc., Dalton Trans. (1998) 3517; (c) O. Pàmies, M. Diéguez, G. Net, A. Ruiz and C. Claver, J. Chem. Soc., Dalton Trans. (1999) 3439; (d) J.C. Bayón, C. Claver and A.M. Masdeu-Bultó, Coord. Chem. Rev. 193–195 (1999) 73; (e) O. Pàmies, G. Net, A. Ruiz, C. Claver and S. Woodward, Tetrahedron: Asymmetry 11 (2000) 871; (f) S. Jansat, M. Gómez, G. Muller, M. Diéguez, A. Aghmiz, C. Claver, A.M. Masdeu-Bultó, L. Flores-Santos, E. Martin, M.A. Maestro and J. Mahía, Tetrahedron: Assymetry 12 (2001) 1469.

  11. H.A. Ankersmit, N. Veldman, A. Spek, K. Eriksen, K. Goubitz, K. Vrieze and G. van Koten, Inorg. Chim. Acta 252 (1996) 203.

    Google Scholar 

  12. P.W.N.M. van Leeuwen, P.C.J. Kamer, J.N.H. Reek and P. Dierkes, Chem. Rev. 100 (2000) 2741.

    Google Scholar 

  13. S.R. Bahr and P.J. Boudjouk, J. Org. Chem. 57 (1992) 5545.

    Google Scholar 

  14. R.E. Rülke, J.M. Ernsting, A.L. Spek, C.J. Elsevier, P.W.N.M. van Leeuwen and K. Vrieze, Inorg. Chem. 32 (1993) 5769.

    Google Scholar 

  15. Ligand 1: A. Gomis, G. Net, A. Ruiz, C. Claver and A. Alvarez-Larena, Inorg. Chim. Acta 325 (2001) 58; (b) Ligand 2: D. Fabbri, S. Pulacchini and S. Gladiali, Synlett 11 (1996) 1019.

    Google Scholar 

  16. E.W. Abel, S.K. Bhargava and K.G. Orrell, Prog. Inorg. Chem. 32 (1984) 1.

    Google Scholar 

  17. M. Diéguez, A. Ruiz, A.M. Masdeu-Bultó and C. Claver, J. Chem. Soc., Dalton Trans. (2000) 4154.

  18. M. Brookhart, F.C. Rix and J.M. DeSimone, J. Am. Chem. Soc. 114 (1992) 5894.

    Google Scholar 

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Authors and Affiliations

  1. Departament de Química Física i Inorgànica and Institut d'Estudis Avançats, Universitat Rovira i Virgili Pl, Imperial T´rraco I, 43005, Tarragona, Spain

    Amaia Bastero, Carmen Claver & Aurora Ruiz

Authors
  1. Amaia Bastero
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  2. Carmen Claver
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  3. Aurora Ruiz
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Bastero, A., Claver, C. & Ruiz, A. Bis-(thio)ethers as Chelating Ligands for the Pd-Catalyzed Alternating CO/tert-Butylstyrene Copolymerization. Catalysis Letters 82, 85–88 (2002). https://doi.org/10.1023/A:1020548326225

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  • DOI: https://doi.org/10.1023/A:1020548326225

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