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State of Hydrogen in Cubic Zirconium Dihydride

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Abstract

PMR spectra have been recorded and the proton spin–lattice relaxation time has been measured for cubic hydride δ-ZrH2. It is found that above 290 K thermally activated diffusion of hydrogen takes place. In the region 230 K, a reversible phase transition takes place, which is due to a change in the state of hydrogen in the crystal lattice of zirconium dihydride. Possible mechanisms of this transition are discussed.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Ekaterinburg

    R. N. Pletnev, A. Ya. Kupryazhkin, A. V. Dmitriev & E. V. Zabolotskaya

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  1. R. N. Pletnev
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  2. A. Ya. Kupryazhkin
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  3. A. V. Dmitriev
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  4. E. V. Zabolotskaya
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Pletnev, R.N., Kupryazhkin, A.Y., Dmitriev, A.V. et al. State of Hydrogen in Cubic Zirconium Dihydride. Journal of Structural Chemistry 43, 445–448 (2002). https://doi.org/10.1023/A:1020337132353

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