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Refinement of the Theory of Electrodissolution of Difficultly-Soluble Compounds from Metal Surfaces: Taking into Account Nonuniform Film Thickness Along the Electrode Surface

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Abstract

An equation that describes the electrodissolution of a film of a difficultly-soluble compound from the surface of metallic electrode during a linear potential scan is derived and solved numerically. The model accounts for a nonuniform deposit distribution over the electrode surface and for the diffusion of the deposit particles through the film. Voltammograms for the compound electroreduction display peaks whose shape is dependent on the deposit distribution over thickness. The obtained results are analyzed.

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REFERENCES

  1. Chemezova, K.S., Khlynova, N.M., and Ageeva, O.S., Elektrokhimiya, 2000, vol. 36, p. 763.

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  2. Vydra, F., Stulik, K., and Julakova, E., Inverse Voltamperometry, Prague: SNTL, 1977.

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  3. Khlynova, N.M., Cand. Sci. (Chem.) Dissertation, Tyumen', 1983, p. 179.

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Authors and Affiliations

  1. Tyumen State University of Oil and Gas, ul. Volodarskogo 38, Tyumen, 625000, Russia

    K. S. Chemezova, N. M. Khlynova & O. V. Sannikova

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  1. K. S. Chemezova
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  2. N. M. Khlynova
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  3. O. V. Sannikova
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Chemezova, K.S., Khlynova, N.M. & Sannikova, O.V. Refinement of the Theory of Electrodissolution of Difficultly-Soluble Compounds from Metal Surfaces: Taking into Account Nonuniform Film Thickness Along the Electrode Surface. Russian Journal of Electrochemistry 38, 1037–1040 (2002). https://doi.org/10.1023/A:1020257515476

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  • DOI: https://doi.org/10.1023/A:1020257515476

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