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Synthesis and Extraction Study of Calix[4]arene Dinitrile Derivatives Incorporated in a Polymeric Backbone with Bisphenol-A

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Abstract

Two new copolymers containing pendant calix[4]arene units with nitrile functionalities at their lower rim have been synthesized via nucleophilic substitution reactions involving 5,11,17,23-tetra-tert-butyl-25,27-bis(cyanomethoxy)-26,28-dihydroxy-calix[4]arene (3) or 25,27-bis(cyanometh oxy)-26,28-dihydroxy-calix[4]arene (4) with 1,5-dibromopentane and bisphenol-A. The phase transfer studies were performed by using liquid–liquid extraction procedures. It has been deduced from the observations that both copolymers show a good phase transfer affinity toward selected alkali, alkaline earth, and transition metal cations, unlike their precursor (3).

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Authors and Affiliations

  1. Department of Chemistry, Campus, Selçuk University, 42031, Konya, Turkey

    Shahabuddin Memon, Oguz Oguz, Aydan Yilmaz, Mustafa Tabakci, Mustafa Yilmaz & Şeref Ertul

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  1. Shahabuddin Memon
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  2. Oguz Oguz
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  3. Aydan Yilmaz
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  4. Mustafa Tabakci
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Correspondence to Mustafa Yilmaz.

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Memon, S., Oguz, O., Yilmaz, A. et al. Synthesis and Extraction Study of Calix[4]arene Dinitrile Derivatives Incorporated in a Polymeric Backbone with Bisphenol-A. Journal of Polymers and the Environment 9, 97–101 (2001). https://doi.org/10.1023/A:1020256907414

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