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Crystal structure of the molecular adduct of 5-mono[(4-nitrophenyl)azo]-25,26,27,28-tetrahydroxycalix[4]arene with chloroform (1:1)

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Abstract

The crystal structure of the molecular adduct of 5-mono[(4-nitrophenyl)azo]-25,26,27,28-tetrahydroxycalix[4]arene (2) with chloroform (C34H27N3O6 ⋅ CHCl3) was determined by X-ray crystallographic analysis. It was found to possess a monoclinic space group P2(1)/n, with a = 15.9306(13) Å, b = 10.6293(9) Å, c = 20.3194(17) Å, β = 110.480(2)° and Dcalc = 1.428 Mg/m3 for Z = 4. Crystal data indicated that the calix[4]arene moiety of 2 exists in a distorted-cone conformation with intramolecular hydrogen bonds.

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Authors and Affiliations

  1. Department of Chemistry, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, People's Republic of China

    Chuan-Ming Jin, Zheng Wang, Kou-Lin Zhang, Guo-Yuan Lu & Xiao-Zeng You

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  1. Chuan-Ming Jin
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  2. Zheng Wang
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  3. Kou-Lin Zhang
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  4. Guo-Yuan Lu
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  5. Xiao-Zeng You
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Correspondence to Guo-Yuan Lu.

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Jin, CM., Wang, Z., Zhang, KL. et al. Crystal structure of the molecular adduct of 5-mono[(4-nitrophenyl)azo]-25,26,27,28-tetrahydroxycalix[4]arene with chloroform (1:1). Journal of Chemical Crystallography 32, 293–297 (2002). https://doi.org/10.1023/A:1020253423983

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