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Excess Molar Volumes and Viscosities of Binary Mixtures of Methanol and the Ionic Liquid 4-Methyl-N-butylpyridinium Tetrafluoroborate at 25, 40, and 50°C

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Abstract

Experimental data of densities and viscosities are presented for the system 4-methyl-N-butylpyridinium tetrafluoroborate + methanol at 25, 40, and 50, 323.15 K and ambient pressure using a vibratage-tube densimeter and an Ubbelohde viscometer. Excess molar volumes V E and excess logarithm viscosities (ln η)E have been determined. V E is negative and (ln η)E positive over the entire mixture composition.

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References

  1. P. Wasserscheid and W. Keim, Angew. Chem. Intern. Ed. 39, 3772(2000).

    Google Scholar 

  2. C. L. Hussey, Pure Appl. Chem. 60, 1763(1988).

    Google Scholar 

  3. C. J. Adams, M. J. Earle, G. Roberts, and K. R. Seddon, Chem. Commun, p. 2097(1998).

  4. K. K. Laali and V. J. Gettwert, J. Org. Chem. 65, 35(2001).

    Google Scholar 

  5. A. S. Larsen, J. D. Holbrey, F. S. Tham, and C. D. Reedm, J. Amer. Chem. Soc. 122, 7264(2000).

    Google Scholar 

  6. H. L. Ngo, K. LeCompte, L. Hargens, and A. B. McEwen, Thermochim. Acta 357, 97(2000).

    Google Scholar 

  7. M. S. Selvan, M. D. McKinley, R. H. Dubois, and J. L. Atwood, J. Chem. Eng. Data 45, 841(2000).

    Google Scholar 

  8. Q. Liao and C. L. Hussey, J. Chem. Eng. Data 41, 1126(1996).

    Google Scholar 

  9. A. Heintz, D. V. Kulikov, and S. P. Verevkin, J. Chem. Eng. Data 46, 1526(2001).

    Google Scholar 

  10. A. Heintz, D. V. Kulikov, and S. P. Verevkin, J. Chem. Eng. Data, in press (2002).

  11. A. Heintz, D. V. Kulikov, and S. P. Verevkin, J. Chem. Thermodyn, in press (2002).

  12. P. Wasserschied, Institut fuer Technische Chemie und Makromolekulare Chemie, RWTH Aachen, Worriger Weg, D-52074 Aachen. email:wasserscheidp@itc.rwth-aachen.de

  13. P. Haraschta, A. Heintz, J. K. Lehmann, and A. Peters, J. Chem. Eng. Data 44, 932(1999).

    Google Scholar 

  14. A. Heintz, B. Schmittecker, D. Wagner, and R. N. Lichtenthaler, J. Chem. Eng. Data 31, 487(1986).

    Google Scholar 

  15. K. R. Seddon, A. Stark, and M. J. Torres, Pure Appl. Chem. 72, 2275(2000).

    Google Scholar 

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Authors and Affiliations

  1. Department of Physical Chemistry, University of Rostock, D-18051, Rostock, Germany

    Andreas Heintz, Dagmar Klasen & Jochen K. Lehmann

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  1. Andreas Heintz
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  2. Dagmar Klasen
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  3. Jochen K. Lehmann
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Heintz, A., Klasen, D. & Lehmann, J.K. Excess Molar Volumes and Viscosities of Binary Mixtures of Methanol and the Ionic Liquid 4-Methyl-N-butylpyridinium Tetrafluoroborate at 25, 40, and 50°C. Journal of Solution Chemistry 31, 467–476 (2002). https://doi.org/10.1023/A:1020217612751

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  • DOI: https://doi.org/10.1023/A:1020217612751

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