Skip to main content
SpringerLink
Log in

Synthesis and crystal structure of copper(II) complex with 1,9-diamino-5-methyl-5-nitro-3,7-diazanonane

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

Condensation of bis(ethanediamine)copper(II) perchlorate with formaldehyde and nitroethane in basic methanol was found to generate (1,9-diamino-5-methyl-5-nitro-3,7-diazanonane)copper(II) perchlorate, [Cu(L1)](ClO4)2. The copper(II) complex was characterized by elemental analysis and infrared and electronic spectra studies. The structure of [Cu(L1)](ClO4)2 was determined by X-ray diffraction. The crystal structure revealed that the copper ion is in an elongated octahedral coordination with four nitrogens at the equational position and perchlorate anions at the axial positions and that one of the perchlorate anions bridges two copper ions, leading to a linear polymeric structure in the crystal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Hancock, R.D.; Martell, A.E. Chem. Rev. 1989, 89, 1875.

    Google Scholar 

  2. Bernhardt, P.V.; Lawrance, G.A. Coord. Chem. Rev. 1990, 104, 297.

    Google Scholar 

  3. de Martino Norante, G.; Di Vaira, M.; Mani, F.; Mazzi, S.; Stoppioni, P. Inorg. Chem. 1990, 29, 2822.

    Google Scholar 

  4. Li, X.; Curits, N.F.; Weathreburn, D.C. Transition Met. Chem. 1992, 17, 147.

    Google Scholar 

  5. Comba, P.; Curits, N.F.; Lawrance, G.A.; O'Leary, M.A.; Slelton, B.W.; White, A.H. J. Chem. Soc., Dalton Trans. 1988, 497.

  6. Curits, N.F.; Li, X.; Weatherburn, D.C. Inorg. Chem. 1993, 32, 5838.

    Google Scholar 

  7. International Tables for X-ray Crystallography; Kynoch Press: Birmingham, England (Present distributor: Kluwer Academic Publisher: Dordrecht.), 1974; Vol. IV.

  8. Siemens, SHELXTL, version 5.0; Siemens Industrial Automation Inc: Madision, 1994.

    Google Scholar 

  9. Lawrance, G.A.; Rossignol, M.; Skelton, B.W.; White, A.H. Aust. J. Chem. 1987, 40, 1441.

    Google Scholar 

  10. Bernhardt, P.V.; Lawrance, G.A.; Skelton, B.W.; White, A.H. Aust. J. Chem. 1990, 43, 399.

    Google Scholar 

  11. Nakamoto, K. Infrared and Raman Spectra of Inorganic and Coordination Compounds, 3rd ed; Wiley-Interscience, New York, 1978.

    Google Scholar 

  12. Drew, M.G.B.; McCann, M.; Nelson, S.M. J. Chem. Soc., Dalton Trans. 1981, 1868.

  13. Hathaway, B.J. J. Chem. Soc., Dalton Trans. 1972, 1196.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Hangzhou Teachers College, Hangzhou, 310012, People's Republic of China

    Liang Shen, Guoding Sheng & Zhiqiang Hu

  2. College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou, 310014, People's Republic of China

    Zhimin Jing

Authors
  1. Liang Shen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Guoding Sheng
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Zhiqiang Hu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Zhimin Jing
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Liang Shen.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shen, L., Sheng, G., Hu, Z. et al. Synthesis and crystal structure of copper(II) complex with 1,9-diamino-5-methyl-5-nitro-3,7-diazanonane. Journal of Chemical Crystallography 32, 289–292 (2002). https://doi.org/10.1023/A:1020201407145

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1020201407145

Search

Navigation