Abstract
The products of dickite heated in air at 1000 to 1300°C were studied using curve-fitting of transmission and photoacoustic infrared and micro-Raman spectra. The spectra were compared with those of mullite, Al-spinel, corundum, cristobalite, amorphous silica and meta-dickite. Bands that characterize crystalline phases appeared at 1100°C and became stronger with increasing temperature. Mullite, Al-spinel, corundum and amorphous silica were identified by their characteristic bands. The characteristic IR bands of cristobalite overlap those of mullite and amorphous silica, and its presence was therefore established from intensity ratios of the appropriate bands. The research clearly demonstrated the advantage of using curve-fitting for the identification of high temperature phases in the study of the thermal treatment of kaolin-like minerals by infrared and Raman spectroscopy. This technique seems to be a useful method for materials analysis in the ceramic industry.
Similar content being viewed by others
References
D. Arnold, Ceramic theory and cultural process. Cambridge University Press, Cambridge 1985.
R. R. West, in ‘Differential Thermal Analysis’ (R. C. Mackenzie, Ed.) Academic Press, London 1972, Vol. 2, p. 149.
P. Sennet, in ‘Kirk-Othner Encyclopedia of Chemical Technology’, 4th edition, Wiley, New York 1992, Vol. 6, p. 405.
H. H. Murray, in ‘Ullman’s Encyclopedia of Industrial Chemistry’, 5th edition, VCH, Berlin 1985, Vol. A7, p. 109.
M. Belloto, A. Gualtieri, G. Artioli and S. M. Clark, Phys. Chem. Miner., 22 (1995) 207.
D. Massiot, P. Dion, J. F. Alcover and F. Bergaya, J. Amer. Ceram. Soc., 78 (1995) 2940.
J. Dubois, M. Murat, A. Amroune, X. Carbonneau and R. Gardon, Appl. Clay Sci., 10 (1995) 187.
P. Dion, J.-F. Alcover, C. Clinard and D. Tchoubar, J. Mater. Sci., 31 (1996) 5069.
P. Dion, J.-F. Alcover, F. Bergaya, A. Ortega, P. L. Llewellyn and F. Rouquerol, Clay Miner., 33 (1998) 269.
A. Gualtieri and M. Bellotto, Phys. Chem. Miner., 25 (1998) 442.
M. P. Riccardi, B. Messiga and P. Duminuco, Appl. Clay Sci., 15 (1999) 393.
L. Stoch, J. Thermal Anal., 29 (1984) 919.
R. L. Frost and A. M. Vassallo, Clays Clay Miner., 44 (1996) 635.
S. Shoval, M. Boudeulle, S. Yariv, I. Lapides and G. Panczer, Optic. Mater., 16 (2001) 319.
C. T. Johnston, J. Helsen, R. A. Schoonheydt, D. L. Bish and S. F. Angew, Amer. Miner., 83 (1998) 75.
S. Shoval, S. Yariv, K. H. Michaelian, M. Boudeulle and G. Panczer, Clays Clay Miner., 49 (2001) 347.
S. Shoval, B. Champagnon and G. Panczer, J. Thermal Anal., 50 (1997) 203.
S. Shoval, S. Yariv, M. Boudeulle and G. Panczer, in ‘Clays for our future’ (H. Kodama, A. R. Mermut & J. K. Torrance, eds.), ICC 1997, Ottawa, Canada 1999, p. 623.
S. Shoval, B. Champagnon, G. Panczer, M. Gaft and M. Boudeulle, Proc., Semaine Franco-Israelienne, Université Claude Bernard, Lyon, France 1999.
F. Freund, in ‘The infrared spectra of minerals’ (V. C. Farmer ed.), Mineralogical Society, London 1974, p. 465.
H. H. W. Moenke, in ‘The infrared spectra of minerals’ (V. C. Farmer ed.), Mineralogical Society, London 1974, p. 365.
S. Mishirky, S. Yariv and Siniarsky, Clay Sci., 4 (1974) 213.
H. W. Van der Marel and H. Beutelspacher, ‘Atlas of infrared spectroscopy of clay minerals and their admixtures’. Elsevier 1976.
A. N. Lazarev, in ‘The Infrared Spectra of Minerals’ (V. C. Farmers ed.) Mineralogical Society, London 1974, p. 69.
S. Yariv, Clay Miner., 21 (1986) 925.
T. Sato, ‘Preparation of aluminium hydroxides and aluminas’, Litarvan Literature, Nedherland, Colorado 1996.
S. M. Bradley, R. A. Kydd and R. F. Howe, J. Coll. Int. Sci., 159 (1993) 405.
C. H. Ruscher, Phys. Chem. Miner., 23 (1996) 50.
B. Champagnon, G. Panczer, C. Chemarin and B. Humbert-Labeaumaz, J. Non-Crystal. Solids, 196 (1996) 221.
N. Q. Liem, G. Sagon, V. X. Quang, H. V. Tan and P. Colomban, J. Raman Spect., 31 (2000) 933.
B. Humbert, A. Burneau, J. P. Gallas and J. C. Lavally, J. Non-Crystal. Solids, 143 (1992) 75.
H. J. Percival, J. Duncan and P. K. Foster, J. Amer. Ceram. Soc., 57 (1974) 57.
S. Shoval, Thermochim. Acta, 135 (1988) 243.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Shoval, S., Michaelian, K.H., Boudeulle, M. et al. Study of thermally treated dickite by infrared and micro-Raman spectroscopy using curve-fitting technique. Journal of Thermal Analysis and Calorimetry 69, 205–225 (2002). https://doi.org/10.1023/A:1019954227093
Issue Date:
DOI: https://doi.org/10.1023/A:1019954227093