Abstract
The syntheses of triisopropyl borate and other boric acid esters under conditions of mechanochemical activation with the use of zeolite catalysts were found to be highly efficient. The proposed method exhibits the following advantages over known methods: short synthesis times, low energy consumption, higher yields of target products, and the absence of byproducts. The mechanism of the catalytic esterification of boric acid under conditions of mechanochemical activation is discussed.
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REFERENCES
Molchanov, V.V. and Buyanov, R.A., Usp. Khim., 2000, vol. 69, no. 5, p. 476.
Gertsev, V.V. and Romanov, Yu.A., Zh. Prikl. Khim., 1992, vol. 65, no. 2, p. 375.
Haider, S.Z., Khundkar, M.H., and Siddiqullah, M., J. Pol. Chem., 1954, no. 4, part 2, p. 93.
Shtenberg, Kh. and Khanter, D.L., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 1958, no. 3, p. 69.
Steinberg, H. and Hunter, D.L., Ind. Eng. Chem., Prod. Res. Dev., 1957, vol. 49, no. 2, p. 174.
Obshchaya organicheskaya khimiya (General Organic Chemistry), Kochetkov, N.K., Ed., 1984, vol. 6, p. 511.
Kamars, A.E., Shvarts, E.M., and Shcherbakov, V.A., Izv. Akad. Nauk LatvSSR, Ser. Khim., 1981, no. 5, p. 610.
Shvarts, E.M., Vzaimodeistvie bornoi kisloty so spirtami i oksikislotami (Interaction of Boric Acid with Alcohols and Oxyacids), Riga: Zinatie, 1990.
Steinberg, H., Organoboron Chemistry, New York, 1964.
Cole, T.E., Quintanilla, R., and Rodewald, S., Synth. React. Inorg. Met-Org. Chem., 1990, vol. 20, no. 1, p. 55.
Konovalova, T.A., Volodin, A.M., Chesnokov, V.V., et al., React. Kinet. Catal. Lett., 1991, vol. 43, no. 1, p. 225.
Brown, H.C., Srebnik, M., and Cole, T.E., Organometallics, 1986, vol. 5, no. 11, p. 2300.
Tkachev, K.V. and Plyshevskii, Yu.S., Tekhnologiya neorganicheskikh soedinenii bora (Technology of Inorganic Boron Compounds), Leningrad, 1983.
Buyanov, R.A., Zolotovskii, B.P., and Molchanov, V.V., Sib. Khim. Zh., 1992, no. 2, p. 5.
Babenko, V.S., Molchanov, V.V., and Konovalova, T.A., Kinet. Katal., 1998, vol. 39, no. 1, p. 62.
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Molchanov, V.V., Goidin, V.V., Golovin, A.V. et al. Application of Mechanochemical Catalysis to the Synthesis of Boric Acid Esters. Kinetics and Catalysis 43, 536–542 (2002). https://doi.org/10.1023/A:1019883219843
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DOI: https://doi.org/10.1023/A:1019883219843