Skip to main content
SpringerLink
Log in

Effect of Bismuth Additives on the Properties of Vanadium–Phosphorus Oxide Catalyst in the Partial Oxidation of n-Pentane

  • Published:
Kinetics and Catalysis Aims and scope Submit manuscript

Abstract

The selective oxidation of n-pentane on vanadium–phosphorus oxide (VPO) catalysts with bismuth additives (Bi/V = 0–0.30) is studied. The catalysts are characterized by XRD, XPS, and specific surface area measurements using nitrogen adsorption. Their acidic properties are studied (using ammonia TPD and the 2-methyl-3-butyn-2-ol reaction). It was found that the introduction of bismuth insignificantly affects the specific surface area but increases the surface concentration of phosphorus and changes the acidic properties of the catalysts. The specific catalytic activity of samples in n-pentane oxidation correlates with the effective charge of surface oxygen (E b of O1s electrons). The selectivity to citraconic anhydride increases with an increase in the general surface acidity. The selectivity to maleic anhydride increases with an increase in the Brønsted acidity of the surface. The selectivity to phthalic anhydride increases with an increase in the Lewis acidity. The pathways of product formation in the partial oxidation of n-pentane are proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Centi, G., Burattini, M., and Trifiro, F., Appl. Catal., 1987, vol. 32, no. 2, p. 353.

    Google Scholar 

  2. Centi, G. and Trifiro, F., Chem. Eng. Sci., 1990, vol. 45, no. 8, p. 2589.

    Google Scholar 

  3. Centi, G., Lopez Nieto, J., Pinelli, D., Trifiro, F., and Ungarelli, F., Stud. Surf. Sci. Catal., 1990, vol. 55, p. 635.

    Google Scholar 

  4. Sobalik, Z., Gonzalez, S., and Ruiz, P., Stud. Surf. Sci. Catal., 1995, vol. 91, p. 727.

    Google Scholar 

  5. Michalakos, P.M., Birkeland, K., and Kung, H.H., J. Catal., 1996, vol. 158, no. 2, p. 349.

    Google Scholar 

  6. Ozkan, U.S., Gooding, R.E., and Schilf, B.T., Heterogeneous Hydrocarbon Oxidation (211th ACS National Meeting), New Orleans, 1996, vol. 41, no. 1, p. 176.

    Google Scholar 

  7. Zazhigalov, V.A., Haber, J., Stoch, J., Mikhajluk, B.D., Pyatnitskaya, A.I., Komashko, G.A., and Bacherikova, I.V., Catal. Lett., 1996, vol. 37, no. 1, p. 95.

    Google Scholar 

  8. Zazhigalov, V.A., Mikhailyuk, B.D., Stokh, E., Bacherikova, I.V., Golovatyi, V.G., and Shabel'nikov, V.P., Teor. Eksp. Khim., 1996, vol. 32, no. 3, p. 186.

    Google Scholar 

  9. Ozkan, U.S., Harris, T.A., and Schilf, B.T., Catal. Today, 1997, vol. 33, no. 1, p. 57.

    Google Scholar 

  10. Sobalik, Z., Gonzalez Carrazan, S., Ruiz, P., and Delmon, B., J. Catal., 1999, vol. 185, no. 2, p. 272.

    Google Scholar 

  11. Calestani, G., Cavani, F., Duran, A., Mazzoni, G., Stefani, G., Trifiro, F., and Venturoli, P., Stud. Surf. Sci. Catal., 1995, vol. 92, p. 179.

    Google Scholar 

  12. Albonetti, S., Cavani, F., Trifiro, F., Venturoli, P., Calestani, G., Lopez Granados, M., and Fierro, J.L.G., J. Catal., 1966, vol. 160, no. 1, p. 52.

    Google Scholar 

  13. Cavani, F., Colombo, A., Trifiro, F., Sananes Schulz, M.T., Volta, J.C., and Hutchings, G.J., Catal. Lett., 1997, vol.43, no. 3, p. 241.

    Google Scholar 

  14. Cavani, F., Colombo, A., Giuntoli, F., Gobbi, E., Trifiro, F., and Vazquez, P., Catal. Today, 1996, vol. 32, no. 1, p. 125.

    Google Scholar 

  15. Busca, G. and Centi, G., J. Am. Chem. Soc., 1989, vol. 111, no. 1, p. 46.

    Google Scholar 

  16. Centi, G., Golinelli, G., and Busca, G., J. Phys. Chem., 1990, vol. 94, no. 17, p. 6813.

    Google Scholar 

  17. Golinelli, G. and Gleaves, J.T., J. Mol. Catal., 1992, vol. 73, no. 3, p. 353.

    Google Scholar 

  18. Cavani, F. and Trifiro, F., Appl. Catal., 1997, vol. 157, nos. 1–2, p. 195.

    Google Scholar 

  19. Hutchings, G., Appl. Catal., 1991, vol. 72, no. 1, p. 1.

    Google Scholar 

  20. Yamazoe, N., Morishige, H., Tamaki, J., and Miura, N., Stud. Surf. Sci. Catal., 1993, vol. 75, p. 1989.

    Google Scholar 

  21. Ruiz, P., Bastians, Ph., Caussin, L., Reuse, R., Dasa, L., Acosta, D., and Delmon, B., Catal. Today, 1993, vol. 16, no. 1, p. 99.

    Google Scholar 

  22. Zazhigalov, V.A., Haber, J., Stoch, J., Pyatnitskaya, A.I., Komashko, G.A., and Belousov, V.M., Appl. Catal., 1993, vol. 96, no. 1, p. 135.

    Google Scholar 

  23. Hodnett, B.K., Permanne, Ph., and Delmon, B., Appl. Catal., 1983, vol. 6, no. 2, p. 231.

    Google Scholar 

  24. Coulston, G.W., Thompson, E.A., and Herron, N., J. Catal., 1996, vol. 163, no. 1, p. 122.

    Google Scholar 

  25. Stoch, J., Podobinski, J., and Zazhigalov, V.A., Abstracts of Papers, EUROPACAT-IV, Rimini, 1999, p. 671.

  26. Lauron-Pernot, H., Luck, F., and Popa, J.M., Appl. Catal., 1991, vol. 78, no. 2, p. 213.

    Google Scholar 

  27. Audry, F., Hoggan, P.E., Saussey, J., Lavalley, J.C., Lauron-Pernot, H., and Le Govic, A.M., J. Catal., 1997, vol. 168, no. 2, p. 471.

    Google Scholar 

  28. Nefedov, V.I. Rentgenoelektronnaya spektroskopiya khimicheskikh soedinenii (X-ray Electron Spectroscopy of Chemical Compounds), Moscow: Khimiya, 1984.

    Google Scholar 

  29. Zazhigalov, V.A., Konovalova, N.D., and Stokh, E., Kinet. Katal., 1988, vol. 29, no. 2, p. 419.

    Google Scholar 

  30. Busca, G., Centi, G., Trifiro, F., and Lorenzelli, V., J. Phys. Chem., 1986, vol. 90, no. 7, p. 1337.

    Google Scholar 

  31. Satsuma, A., Hattori, A., Furuta, A., Miyamoto, A., Hattori, T., and Murakami, Y., J. Phys. Chem., 1988, vol. 92, no. 12, p. 2275.

    Google Scholar 

  32. Ruiz, P., Bastians, Ph., Caussin, L., Reuse, R., Dasa, L., Acosta, D., and Delmon, B., Catal. Today, 1993, vol. 16, no. 1, p. 99.

    Google Scholar 

  33. Berndt, H., Buker, K., Martin, A., Bruckner, A., and Lucke, B., J. Chem. Soc., Faraday Trans., 1995, vol. 91, no. 5, p. 725.

    Google Scholar 

  34. Centi, G. and Perathoner, S., J. Catal., 1993, vol. 142, no. 1, p. 84.

    Google Scholar 

  35. Nikolov, V., Klissurski, D., and Anastasov, A., Catal. Rev.-Sci. Eng., 1991, vol. 33, no. 3, p. 319.

    Google Scholar 

  36. Sokolovskii, V.D., Catal. Rev.-Sci. Eng., 1990, vol. 32, no. 1, p. 1.

    Google Scholar 

  37. Zazhigalov, V.A., Haber, J., Stoch, J., Bacherikova, I.V., Komashko, G.A., and Pyatnitskaya, A.I., Appl. Catal., A, 1996, vol. 134, no. 2, p. 225.

    Google Scholar 

  38. Novak, Ya. and Gerei, Sh., Geterogennyi kataliz (Heterogeneous Catalysis), Sofia: Bulgar. Akad. Nauk, 1983, vol. 1, p. 171.

    Google Scholar 

  39. Ziolkowski, J., Bordes, E., and Courtine, P., J. Catal., 1990, vol. 122, no. 1, p. 126.

    Google Scholar 

  40. Ziolkowski, J., Bordes, E., and Courtine, P., J. Mol. Catal., 1993, vol. 84, no. 2, p. 307.

    Google Scholar 

  41. Zazhigalov, V.A., Heterogeneous Hydrocarbon Oxidation (211th ACS National Meeting), New Orleans, 1996, vol. 41, no. 1, p. 207.

    Google Scholar 

  42. Zazhigalov, V.A., Teor. Eksp. Khim., 1999, vol. 35, no. 5, p. 265.

    Google Scholar 

  43. Chakir, A., Cathonnet, M., Boettner, J.C., and Gaillard, F., Combust. Sci. Tech., 1989, vol. 65, no. 2, p. 207.

    Google Scholar 

  44. Centi, G., Trifiro, F., Ebner, J.R., and Franchetti, V.M., Chem. Rev., 1988, vol. 88, no. 1, p. 55.

    Google Scholar 

  45. Seeboth, H., Kubias, B., Wolf, H., and Lucke, B., Chem. Tech., 1978, vol. 28, no. 7, p. 730.

    Google Scholar 

  46. Ingold, C.K., Structure and Mechanism in Organic Chemistry, Ithaca: Cornell Univ., 1969.

    Google Scholar 

  47. Centi, G., Lopez Nieto, J., Ungarelli, F., and Trifiro, F., Catal. Lett., 1990, vol. 4, no. 3, p. 309.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Ukranian–Polish Laboratory of Catalysis, Institute of Sorption and the Problems of Endoecology, National Academy of Sciences of Ukraine, Kiev, 03164, Ukraine

    V. A. Zazhigalov

Authors
  1. V. A. Zazhigalov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zazhigalov, V.A. Effect of Bismuth Additives on the Properties of Vanadium–Phosphorus Oxide Catalyst in the Partial Oxidation of n-Pentane. Kinetics and Catalysis 43, 514–521 (2002). https://doi.org/10.1023/A:1019827002097

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1019827002097

Keywords

Search

Navigation