Skip to main content
SpringerLink
Log in

Theoretical Models for Calculating the Kinetics of Luminescence Spectra with Allowance for the Effect of Quantum Beats under Molecular Isomerization

  • Published:
Journal of Applied Spectroscopy Aims and scope

Abstract

On the basis of the previously developed approach to the description of molecular transformations we propose two theoretical models for analyzing the process of intramolecular energy dissipation with allowance for the nonradiative isomer‐isomer transitions. Examples of kinetic curves for the level populations as functions of time in the presence of quantum beats associated with isomerization are given.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. M. Ivanco, J. Hager, W. Sharfin, and S. C. Wallace, J. Chem. Phys., 78, 6531–6540 (1983).

    Google Scholar 

  2. A. A. Heikal, J. S. Baskin, L. Ban#ares, and A. H. Zewail, J. Phys. Chem. A, 101, 572–590 (1997).

    Google Scholar 

  3. W. R. Lambert, P. M. Felker, and A. H. Zewail, J. Chem. Phys., 81, No. 5, 2217–2232 (1984).

    Google Scholar 

  4. S. Takenchi and N. Tahara, Chem. Phys. Lett., 326, 430–438 (2000).

    Google Scholar 

  5. W. R. Lambert, P. M. Felker, and A. H. Zewail, J. Chem. Phys., 75, 5958–5966 (1981).

    Google Scholar 

  6. L. A. Gribov, V. I. Baranov, and D. Yu. Zelentsov, Electron-Vibrational Spectra of Polyatomic Molecules. Theory and Methods of Calculation [in Russian], Moscow (1997).

  7. L. A. Gribov, V. I. Baranov, and S. A. Astakhov, Dokl. Ross. Akad. Nauk, 374, No. 4, 493–498 (2000).

    Google Scholar 

  8. S. A. Astakhov and V. I. Baranov, Opt. Spektrosk., 90, No. 2, 237–245 (2001).

    Google Scholar 

  9. S. A. Astakhov, V. I. Baranov, and L. A. Gribov, Zh. Anal. Khim., 56, No. 7, 703–713 (2001).

    Google Scholar 

  10. L. A. Gribov, From the Theory of Spectra to the Theory of Chemical Conversion [in Russian], Moscow (2001).

  11. A. K. Chibisov, Usp. Khim., 39, Issue 10, 1886–1911 (1983).

    Google Scholar 

  12. A. K. Chibisov, Zh. Anal. Khim., 38, Issue 6, 1104–1130 (1983).

    Google Scholar 

  13. L. S. Atabekyan and A. K. Chibisov, J. Photochem., 31, 123–130 (1985).

    Google Scholar 

  14. A. K. Chibisov, G. V. Zakharova, V. L. Shapovalov, A. I. Tolmachev, Yu. L. Briks, Yu. L. Slonimskii, Khim. Vys. Énergii, 29, No. 3, 211–218 (1995.

    Google Scholar 

  15. A. K. Chibisov and H. Gorner, J. Phys. Chem. A, 101, No. 24, 4305–4312 (1997).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. V. I. Vernadskii Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, 19, Kosygina Str., Moscow, V‐334, GSP‐1, 119991, Russia

    L. A. Gribov

Authors
  1. L. A. Gribov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Gribov, L.A. Theoretical Models for Calculating the Kinetics of Luminescence Spectra with Allowance for the Effect of Quantum Beats under Molecular Isomerization. Journal of Applied Spectroscopy 69, 357–363 (2002). https://doi.org/10.1023/A:1019790830244

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1019790830244

Search

Navigation