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Synthesis, Formation Mechanism, and Crystal Structure of the Nitrosoruthenium(II) Nitrochloride Complex Fac-K2[RuNO(NO2)2Cl3]

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Abstract

Procedures for synthesis of the first nitrochloride complex of nitrosoruthenium(II), fac-K2[RuNO(NO2)2Cl3], are described and the mechanism of its formation is suggested. The compound was investigated by IR spectroscopy and X-ray phase and X-ray diffraction analyses. Crystal data for Cl3N3O5K2Ru: a = 7.050(1), b = 7.524(2), c = 10.125(2) Å, α = 90.44(3), β = 103.17(3), γ = 90.51(3)°, V = 522.9 Å3, space group \(P\bar 1\), Z = 2, d calc = 2.589 g/cm3. The structure consists of the complex anions fac-[RuNO(NO2)2Cl3]2– and K+ cations. The complex crystallizes as triclinic plates and red orange prisms; it is well soluble in water, not readily soluble in KCl solutions, and insoluble in ethanol and acetone; the complex is stable when stored in air.

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  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    V. A. Emel'yanov, I. A. Baidina, S. A. Gromilov, A. V. Virovets & A. V. Belyaev

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  1. V. A. Emel'yanov
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  2. I. A. Baidina
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  3. S. A. Gromilov
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  4. A. V. Virovets
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  5. A. V. Belyaev
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Emel'yanov, V.A., Baidina, I.A., Gromilov, S.A. et al. Synthesis, Formation Mechanism, and Crystal Structure of the Nitrosoruthenium(II) Nitrochloride Complex Fac-K2[RuNO(NO2)2Cl3]. Journal of Structural Chemistry 43, 304–311 (2002). https://doi.org/10.1023/A:1019656609344

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