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The Mn(acac)3—RCN—CCl4 system as a new efficient reagent for the oxidation of secondary alcohols into ketones

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Abstract

The Mn(acac)3—RCN—CCl4 system was found to be efficient for the oxidation of secondary alcohols into the corresponding ketones in 80—93% yields. The oxidation proceeds through the formation of alkyl hypochlorites, which are generated from CCl4 and the alcohols in the presence of the Mn(acac)3—RCN catalytic system (R = Me, Et, and Ph).

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Authors and Affiliations

  1. Academy of Sciences of the Bashkortostan Republic and Ufa Research Center, Russian Academy of Sciences, Institute of Petrochemistry and Catalysis, 141 prosp. Oktyabrya, 450075, Ufa, Russian Federation

    R. I. Khusnutdinov, N. A. Schadneva, A. R. Baiguzina & U. M. Dzhemilev

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  1. R. I. Khusnutdinov
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  2. N. A. Schadneva
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  3. A. R. Baiguzina
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  4. U. M. Dzhemilev
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Khusnutdinov, R.I., Schadneva, N.A., Baiguzina, A.R. et al. The Mn(acac)3—RCN—CCl4 system as a new efficient reagent for the oxidation of secondary alcohols into ketones. Russian Chemical Bulletin 51, 1065–1067 (2002). https://doi.org/10.1023/A:1019638407972

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