Skip to main content
SpringerLink
Log in

Effect of Functionality of Oligophenolic Hardener on Structural and Kinetic Features of Formation and on Properties of Epoxy-Phenolic Cross-Linked Polymers

  • Published:
Russian Journal of Applied Chemistry Aims and scope Submit manuscript

Abstract

Kinetics of the reaction of resorcinol diglycidyl ether with novolac phenol-formaldehyde resins of various functionalities were studied over a wide temperature range by isothermal calorimetry. The effects of the functionality of oligophenols on curing of epoxy-phenolic composites, structure of the resulting polymer at the chemical, topological, and supramolecular levels, its mechanical and relaxation properties, and the mechanism of its fracture were analyzed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Smirnov, Yu.N., Golodkova, F.M., and Dzhavadyan, E.A., Vysokomol. Soedin., Ser. B, 1998, vol. 40, no. 6, pp. 1031-1034.

    Google Scholar 

  2. Smirnov, Yu.N. and Lapitskii, V.A., Zh. Prikl. Khim., 1998, vol. 71, no. 11, pp. 1863-1867.

    Google Scholar 

  3. Smirnov, Yu.N., Golodkova, F.M., and Ponomareva, T.I., Zh. Prikl. Khim., 2000, vol. 73, no. 4, pp. 634-638.

    Google Scholar 

  4. Smirnov, Yu.N. and D'yankova, S.L., Zh. Prikl. Khim., 2000, vol. 73, no. 5, pp. 819-825.

    Google Scholar 

  5. Smirnov, Yu.N., Komarov, B.A., Kushch, P.P., et. al., Zh. Prikl. Khim., 2002, vol. 75, no. 2, pp. 274-285.

    Google Scholar 

  6. Nikolaev, A.F., Sinteticheskie polimery i plasticheskie massy na ikh osnove (Synthetic Polymers and Plastics Based on Them), Moscow: Khimiya, 1964.

    Google Scholar 

  7. Lee, H. and Nevill, K., Handbook of Epoxy Resins, New York: McGraw-Hill, 1967.

    Google Scholar 

  8. Andrievskaya, G.D., Vysokoprochnye orientirovannye stekloplastiki (High-Strength Oriented Glass-Reinforced Plastics), Moscow: Nauka, 1966.

    Google Scholar 

  9. Trizno, M.S. and Nikolaev, A.F., Epoksidno-novolachnye bloksopolimery i oblasti ikh primeneniya (Epoxy-Novolac Block Copolymers and Areas of Their Application), Leningrad: Dom Nauchno-Tekh. Propagandy, 1970.

    Google Scholar 

  10. Kryzhanovskii, V.K., Iznosostoikie reaktoplasty (Wear-Resistant Thermosetting Plastics), Leningrad: Khimiya, 1984.

    Google Scholar 

  11. Smirnov, Yu.N., Naidovskii, E.S., Volkov, V.P., et al., Abstracts of Papers, Vtoraya Vsesoyuznaya konferentsiya po khimii i fizikokhimii polimerizatsionnosposobnykh oligomerov (The 2nd All-Union Conf. on Chemistry and Physical Chemistry of Polymerizable Oligomers), Alma-Ata, 1979, p. 52.

  12. Serenson, W.R. and Campbell, T.W., Preparative Methods of Polymer Chemistry, New York: Interscience, 1961.

    Google Scholar 

  13. Volkov, V.P., Naidovskii, E.S., Komarov, B.A., et al., Vysokomol. Soedin., Ser. A, 1982, vol. 24, no. 12, pp. 2520-2526.

    Google Scholar 

  14. Komarov, B.A., Volkov, V.P., Boiko, G.N., et al., Vysokomol. Soedin., Ser. A, 1983, vol. 25, no. 7, pp. 1431-1435.

    Google Scholar 

  15. Dzhavadyan, E.A., Galyuk, O.S., and Rozenberg, B.A., Zavod. Lab., 1979, no. 3, pp. 228-230.

  16. Siling, M.I., Matyukhina, O.S., Mochalova, O.A., et al., Vysokomol. Soedin., Ser. A, 1969, vol. 11, no. 9, pp. 1943-1951.

    Google Scholar 

  17. Smirnov, Yu.N., Shatskaya, T.E., Natrusov, V.I., and Lapitskii, V.A., Plast. Massy, 1986, no. 7, pp. 24-26.

  18. Geiseler, G. and Seidel, H., Die Wasserstoffbruckenbindung, Berlin: Akademie, 1977.

    Google Scholar 

  19. Pshenitsina, V.P., Shabadash, A.N., and Fremel', T.V., Dokl. Akad. Nauk SSSR, 1963, vol. 153, no. 3, pp. 650-652.

    Google Scholar 

  20. Hale, L., Macosko, Ch.W., and Bair, E., Macromolecules, 1991, vol. 24, pp. 2610-2619.

    Google Scholar 

  21. Oleinic, E.F., Adv. Polym. Sci., 1986, vol. 80, pp. 49-95.

    Google Scholar 

  22. Smirnov, Yu.N. and Volkov, V.P., Plast. Massy, 2001, no. 12, pp. 26-29.

  23. Tarasov, V.P., Smirnov, Yu.N., Erofeev, L.N., et al., Vysokomol. Soedin., Ser. A, 1982, vol. 24, no. 11, pp. 2379-2382.

    Google Scholar 

  24. Smirnov, Yu.N., Rozenberg, B.A., Mileiko, S.T., et al., Plast. Massy, 1984, no. 4, pp. 17-20.

  25. Irzhak, V.I., Rozenberg, B.A., and Enikolopyan, N.S., Setchatye polimery: Sintez, struktura, svoistva (Cross-Linked Polymers: Synthesis, Structure, and Properties), Moscow: Nauka, 1979.

    Google Scholar 

  26. Perepechko, I.I., Akusticheskie metody issledovaniya polimerov (Acoustic Methods in Polymer Research), Moscow: Khimiya, 1973.

    Google Scholar 

  27. Gul', V.E., Struktura i prochnost' polimerov (Structure and Durability of Polymers), Moscow: Khimiya, 1971.

    Google Scholar 

  28. Berry, J.P., Fracture. An Advances Treatise, Liebowitz, H., Ed., vol. 7, part 2: Fracture of Nonmetals and Composites, New York: Academic, 1972.

    Google Scholar 

  29. Smirnov, Yu.N., Irzhak, V.I., and Rozenberg, B.A., Vysokomol. Soedin., Ser. B, 1983, vol. 25, no. 12, pp. 914-916.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Russian Academy of Sciences, Institute for Problems of Chemical Physics, Chernogolovka, Moscow oblast, Russia

    Yu. N. Smirnov & V. P. Volkov

  2. Russian Academy of Sciences, Institute of Synthetic Polymeric Materials, Moscow, Russia

    Yu. N. Smirnov & V. P. Volkov

Authors
  1. Yu. N. Smirnov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. P. Volkov
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Smirnov, Y.N., Volkov, V.P. Effect of Functionality of Oligophenolic Hardener on Structural and Kinetic Features of Formation and on Properties of Epoxy-Phenolic Cross-Linked Polymers. Russian Journal of Applied Chemistry 75, 611–618 (2002). https://doi.org/10.1023/A:1019525332486

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1019525332486

Keywords

Search

Navigation