Skip to main content
SpringerLink
Log in

Preparation, characterization and application of KNH2/Al2O3 and KF/Al2O3 as strong solid bases

  • Published:
Catalysis Surveys from Japan Aims and scope Submit manuscript

Abstract

This review describes the preparation, characterization and application of KNH2 loaded on alumina and KF loaded on alumina. These strong solid bases catalyze a variety of organic reactions in a very selective manner. The reactions include isomerizations of alkenes and alkynes, dimerization of alkynes, Tishchenko reaction, and the reaction of silanes to form of Si–C, Si–N and Si–O bonds.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Baba, H. Handa and Y. Ono, J. Chem. Soc. Faraday Trans. 90 (1994) 187.

    Google Scholar 

  2. Y. Ono and T. Baba, Catalysis Today 38 (1997) 321.

    Google Scholar 

  3. H. Handa, T. Baba, H. Yamada, T. Takahashi and Y. Ono, Catal. Lett. 44 (1997) 119.

    Google Scholar 

  4. T. Baba, A. Kato, H. Handa and Y. Ono, Catal. Lett. 47 (1997) 77.

    Google Scholar 

  5. T. Baba, H. Handa and Y. Ono, Catal. Lett. 50 (1998) 83.

    Google Scholar 

  6. T. Baba, A. Kato, H. Takahashi, F. Toriyama, H. Handa, Y. Ono and H. Sugisawa, J. Catal. 176 (1998) 488.

    Google Scholar 

  7. T. Baba, H. Yuasa, H. Handa and Y. Ono, Catal. Lett. 50 (1998) 83.

    Google Scholar 

  8. T. Ando, Stud. Surf. Sci. Catal. 90 (1994) 9, and references therein.

    Google Scholar 

  9. D.E. Bergbreider and J.J. Lalonde, J. Org. Chem. 52 (1957) 1601.

    Google Scholar 

  10. H. Tsuji, H. Kabashima, H. Kita and H. Hattori, Reac. Kinet. Catal. Lett. 56 (1995) 363.

    Google Scholar 

  11. H. Handa, T. Baba and Y. Ono, J. Mol. Catal. A 134 (1998) 171.

    Google Scholar 

  12. T. Yamaguchi, J.-H. Zhu, Y. Wang, M. Komatu and M. Ookawa, Chem. Lett. (1997) 989.

  13. Y. Fu, T. Baba and Y. Ono, Appl. Catal. A 166 (1998) 425.

    Google Scholar 

  14. Y. Fu, T. Baba and Y. Ono, Appl. Catal. A 176 (1999) 203.

    Google Scholar 

  15. Y. Fu, T. Baba and Y. Ono, Appl. Catal. A 178 (1999) 219.

    Google Scholar 

  16. J. Take, N. Kikuchi and Y. Yoneda, J. Catal. 21 (1974) 164.

    Google Scholar 

  17. K. Tanabe, M. Misono, Y. Ono and H. Hattori, New Solid Acids and Bases, Stud. Surf. Sci. Catal., Vol. 51 (Kodansha-Elsevier, Tokyo-Amsterdam, 1989).

    Google Scholar 

  18. H. Hattori, Chem. Rev. 95 (1995) 527.

    Google Scholar 

  19. T. Baba, R. Koide and Y. Ono, J. Chem. Commun. (1991) 691.

  20. T. Baba, G.-J. Kim and Y. Ono, J. Chem. Soc. Faraday Trans. 88 (1992) 891.

    Google Scholar 

  21. T. Baba, S. Hikita, R. Koide, T. Hanada, T. Tanaka and Y. Ono, J. Chem. Soc. Faraday Trans. 89 (1993) 3177.

    Google Scholar 

  22. T. Baba, S. Hikita, T. Hanada, T. Tanaka, S. Yoshida and Y. Ono, J. Mol. Catal. A 98 (1995) 49.

    Google Scholar 

  23. T. Baba, S. Hikita, H. Handa and Y. Ono, Res. Chem. Intermed. 24 (1998) 495.

    Google Scholar 

  24. H. Handa, Y. Fu, T. Baba and Y. Ono, Catal. Lett. 59 (1999) 195.

    Google Scholar 

  25. A.J. Hurbert and G. Vieche, J. Chem Soc. C (1968) 228.

  26. A.J. Hurbert, Chem. Ind. (1968) 975.

  27. A.J. Hurbert, J. Chem Soc. C (1968) 2048.

  28. H. Handa, T. Baba and Y. Ono, J. Chem. Soc. Faraday Trans. 94 (1998) 451.

    Google Scholar 

  29. A. Corma, V. Fornes, R.M. Martin-Aranda, H. Garcia and J. Primo, Appl. Catal. 59 (1990) 237.

    Google Scholar 

  30. Z.-H. Fu and Y. Ono, J. Catal. 145 (1994) 166.

    Google Scholar 

  31. T. Yashima, K. Sato, T. Hayasaka and N. Hara, J. Catal. 26 (1972) 303.

    Google Scholar 

  32. Z.A. Miyzoyan, G.V. Kovaleva, I.I. Pisman, I.A. Livishits, L.M. Korobova and M.A. Dalin, Dokl. Akad. Nauk SSSR 30 (1974) 28.

    Google Scholar 

  33. T. Baba, T. Endou, H. Handa and Y. Ono, Appl. Catal. A 97 (1993) L19.

    Google Scholar 

  34. H. Kabashima, H. Thuji and H. Hattori, React. Kinet. Catal. Lett. 58 (1996) 255.

    Google Scholar 

  35. G. Suzukamo, M. Fukao and M. Minobe, Chem. Lett. (1987) 585.

  36. G. Suzukamo, M. Fukao, T. Hibi, K. Tanabe and K. Chikaishi, in: Acid-Base Catalysis, eds. K. Tanabe, H. Hattori, T. Yamaguti and T. Tanaka (Kodansha-VCH, Tokyo-Weinheim, 1989) p. 405.

    Google Scholar 

  37. K. Tanabe, H. Yanashima, M. Minobe and G. Suzukamo, Appl. Surf. Sci. 121/122 (1997) 461.

    Google Scholar 

  38. A.Ts. Malkhasyan, Zh.L. Dzhandzhuyan, G.T. Martirosyan and I.P. Beletsskaya, Zh. Org. Khim. 15 (1979) 342.

    Google Scholar 

  39. B.A. Trofimov, L.N. Sobenina, O.V. Petrova and A.I. Mikhalera, Dokl. Akad. Nauk 328 (1993) 29.

    Google Scholar 

  40. Y.-S. Jane and J.-H. Shih, J. Mol. Catal. 89 (1994) 29.

    Google Scholar 

  41. T. Baba, N. Kitsuka, H. Handa and Y. Ono, Appl. Catal. A 194-195 (2000) 203.

    Google Scholar 

  42. D. Tzalis and P. Knochel, Angew. Chem. Int. Ed. 38 (1999) 1436.

    Google Scholar 

  43. R.J.P. Corriu, C. Guerin and J.J.E. Moreau, in: The Chemistry of Organic Silicon Compounds, eds. S. Patai and Z. Rappoport (Wiley, New York, 1989) chapter 4, p. 385.

    Google Scholar 

  44. A.R. Bassindale and R.G. Taylor, in: The Chemistry of Organic Silicon Compounds, eds. S. Patai and Z. Rappoport (Wiley, New York, 1989) chapter 13, p. 839.

    Google Scholar 

  45. R.J. Corriu and C. Guerin, Adv. Organometal. Chem. 20 (1980) 231.

    Google Scholar 

  46. R.J. Corriu, Pure Appl. Chem. 60 (1988) 99.

    Google Scholar 

  47. T. Baba, A. Kato, H. Yuasa, F. Toriyama, H. Handa and Y. Ono, Catal. Today 44 (1998) 271.

    Google Scholar 

  48. K. Tanabe and K. Saito, J. Catal. 35 (1974) 247.

    Google Scholar 

  49. L.M. Weinstock and J.M. Stevenson, Tetrahedron Lett. 27 (1986) 3845.

    Google Scholar 

  50. T. Ando, S.J. Brown, J.H. Cark, P.G. Cork, T. Hanfusa, J. Ichihara, J.M. Miller and M.S. Robertson, J. Chem. Soc. Perkin Trans. 2 (1986) 1133.

    Google Scholar 

  51. C.V.A. Duke and J.M. Miller, J. Mol. Catal. 62 (1990) 233.

    Google Scholar 

  52. J.H. Clark, E.M. Goodman, D.K. Smith, S.J. Brown and J.M. Miller, J. Chem. Soc. Chem. Commun. (1986) 657.

  53. K. Higuchi, M. Onaka and Y. Izumi, Bull. Chem. Soc. Jpn 66 (1993) 2016.

    Google Scholar 

  54. M. Onaka, K. Higuchi, H. Nanami and Y. Izumi, Bull. Chem. Soc. Jpn. 66 (1993) 2638.

    Google Scholar 

Download references

Authors
  1. Toshihide Baba
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Baba, T. Preparation, characterization and application of KNH2/Al2O3 and KF/Al2O3 as strong solid bases. Catalysis Surveys from Asia 4, 17–29 (2000). https://doi.org/10.1023/A:1019092222785

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1019092222785

Search

Navigation