Skip to main content
SpringerLink
Log in

Photoluminescence properties of tetrahedral titanium oxide species in zeolitic materials

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

The photoluminescence spectra of the Y‐type zeolite modified with titanium ions and Ti‐silicalite‐1 have been investigated by varying the excitation energy. A three‐dimensional image of the photoluminescence shows that the peak attributed to tetrahedral titanium oxide species is present at the excitation energy around 200–210 nm, which is consistent with the UV absorption of the samples. The technique enables the distinction of the photoluminescence of the titanium species from that of silicate species.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. M. Taramasso, G. Perego and B. Notari, US Patent 4,410,501.

  2. M. Anpo and H. Yamashita, in: Surface Photochemistry, ed. M. Anpo (Wiley, Chichester, 1996) p. 118.

    Google Scholar 

  3. B. Notari, Catal. Today 18 (1993) 163; Adv. Catal. 41 (1996) 253, and references therein.

    Article  CAS  Google Scholar 

  4. T. Tatsumi, M. Nakamura, S. Negishi and H. Tominaka, J. Chem. Soc. Chem. Commun. (1990) 476.

  5. A. Corma, M.A. Camblor, P. Esteve, A. Martinez and J. Perez-Pariente, J. Catal. 145 (1994) 151.

    Article  CAS  Google Scholar 

  6. T. Maschmeyer, F. Rey, G. Sankar and J.M. Thomas, Nature 378 (1995) 159.

    Article  CAS  Google Scholar 

  7. J.S. Reddy and A. Sayari, J. Chem. Soc. Chem. Commun. (1995) 23.

  8. A. Lopez, M.H. Tuilier, J.L. Guth, L. Delmotte and J.M. Popa, J. Solid State Chem. 102 (1993) 480.

    Article  CAS  Google Scholar 

  9. L. Le Noc, D. Trong On, S. Solomykina, B. Echchahed, F. Béland, C. Cartier dit Moulin and L. Bonneviot, Stud. Surf. Sci. Catal. 101 (1996) 611.

    Article  CAS  Google Scholar 

  10. L. Marchese, T. Maschmeyer, E. Gianotti, S. Coluccia and J.M. Thomas, J. Phys. Chem. 101 (1997) 8836.

    CAS  Google Scholar 

  11. H. Yamashita, Y. Ichihashi, M. Anpo, M. Hashimoto, C. Louis and M. Che, J. Phys. Chem. 100 (1996) 16041.

    Article  CAS  Google Scholar 

  12. Y. Ichihashi, H. Yamashita and M. Anpo, Stud. Surf. Sci. Catal. 105 (1997) 1609.

    Google Scholar 

  13. S.G. Zhang, Y. Ichihashi, H. Yamashita, T. Tatsumi and M. Anpo, Chem. Lett. (1996) 895.

  14. M. Anpo, in: Handbook of Heterogeneous Catalysis, Vol. 2, eds. G. Ertl, H. Knözinger and J. Weitkamp (Wiley-VCH, Weinheim, 1997) p. 664.

    Google Scholar 

  15. M.R. Boccuti, K.M. Rao, A. Zecchina, G. Leofanti and G. Petrini, Stud. Surf. Sci. Catal. 48 (1989) 133.

    Google Scholar 

  16. J.S. Reddy and R.J. Kumar, J. Catal. 130 (1991) 440.

    Article  CAS  Google Scholar 

  17. X. Liu, K.-K. Iu and J.K. Thomas, J. Chem. Soc. Faraday Trans. 89 (1993) 1861.

    Article  CAS  Google Scholar 

  18. Y. Matsumura, K. Hashimoto and S. Yoshida, J. Catal. 117 (1989) 135.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. AIST‐MITI, Osaka National Research Institute, 1‐8‐31, Midorigaoka, Ikeda, Osaka, 563‐8577, Japan

    Yuichi Ichihashi, Yoshie Souma & Yasuyuki Matsumura

  2. Department of Applied Chemistry, Osaka Prefecture University, 1‐1, Gakuencho, Sakai, Osaka, 599‐8531, Japan

    Hiromi Yamashita & Masakazu Anpo

Authors
  1. Yuichi Ichihashi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Hiromi Yamashita
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Masakazu Anpo
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yoshie Souma
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yasuyuki Matsumura
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ichihashi, Y., Yamashita, H., Anpo, M. et al. Photoluminescence properties of tetrahedral titanium oxide species in zeolitic materials. Catalysis Letters 53, 107–109 (1998). https://doi.org/10.1023/A:1019057906526

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/A:1019057906526

Search

Navigation