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Michael addition of ethyl acrylate and acetone over solid bases

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Abstract

The catalytic behaviour of the superbases Na/NaOH/γ-Al2O3 and CsxO/γ-Al2O3 as well as of the basic zeolites Na/NaX and CsxO/CsX were investigated in the Michael addition of ethyl acrylate and acetone. The reactions were carried out in the liquid phase at catalyst loadings varying from 0.05 to 0.1 mol ester/g catalyst.

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References

  1. E.D. Bergman, D. Ginsburg and R. Pappo, Org. React. 10 (1959) 179.

    Google Scholar 

  2. A. Garcia-Raso, J. Garcia-Raso, B. Campaner, R. Mestres and J.V. Sinisterra, Synthesis (1982) 1036.

  3. A.M. de Jong and J.W. Niemantsverdriet, Surf. Sci. 233 (1990) 355.

    Google Scholar 

  4. K.R. Kloetstra and H. van Bekkum, Stud. Surf. Sci. Catal. 105 (1997) 431.

    Google Scholar 

  5. K.R. Kloetstra and H. van Bekkum, J. Chem. Soc. Chem. Commun. (1995) 1005.

  6. G. Suzukamo, M. Fukao, M. Minobe and A. Sakamoto, Eur. Patent 0 211 448 B1 (1990) Sumitomo Chemical Co.

  7. H. Hattori, Mater. Chem. Phys. 18 (1988) 533.

    Google Scholar 

  8. H. Hattori, in: Heterogeneous Catalysis and Fine Chemicals III, Stud. Surf. Sci. Catal., Vol. 78, eds. M. Guisnet et al. (Elsevier, Amsterdam, 1993).

    Google Scholar 

  9. K. Tanabe, M. Misono, Y. Ono and H. Hattori, New Solid Acids and Bases, Stud. Surf. Sci. Catal., Vol. 51 (Elsevier, Amsterdam, 1989).

    Google Scholar 

  10. G. Suzukamo, M. Fukao, T. Hibi, K. Tanaka and K. Chikaishi, in: Acid-Base Catalysis, Proc. Symposium Acid-Base Catalysis, Sapporo, Japan, eds. K. Tanabe et al. (Kodansha, Tokyo, 1989) p. 405.

    Google Scholar 

  11. W.F. Hölderich, in: New Frontiers in Catalysis, Proc. 10th Int. Congr. Catal., Budapest, Hungary, Stud. Surf. Sci. Catal., Vol. 75, eds. L. Guczi et al. (Elsevier, Amsterdam, 1993) p. 127.

    Google Scholar 

  12. G. Suzukamo, M. Fukao, T. Hibi, K. Tanaka and M. Minobe, Stud. Surf. Sci. Catal. 108 (1997) 649.

    Google Scholar 

  13. D. Barthomeuf, Catal. Rev. 38 (1996) 521.

    Google Scholar 

  14. C.B. Dartt and M.E. Davis, Catal. Today 19 (1994) 151.

    Google Scholar 

  15. L.R.M. Martens, W.J. Vermeiren, D.R. Huybrechts, P.J. Grobet and P.A. Jacobs, in: Proc. 9th Int. Congr. Catal., Calgary, Canada, Vol. 1 (Chem. Inst. Canada, Ottawa, 1988) p. 420.

    Google Scholar 

  16. L.R.M. Martens, P.J. Grobet, W.J.M. Vermeiren and P.A. Jacobs, Stud. Surf. Sci. Catal. 28 (1986) 935.

    Google Scholar 

  17. L.R.M. Martens, P.J. Grobet, W.J.M. Vermeiren and P.A. Jacobs, Stud. Surf. Sci. Catal. 31 (1987) 531.

    Google Scholar 

  18. L.R.M. Martens, P.J. Grobet and P.A. Jacobs, Nature 315 (1985) 568.

    Google Scholar 

  19. P.E. Hathaway and M.E. Davis, J. Catal. 116 (1989) 263.

    Google Scholar 

  20. T. Weil, W.H. Müller and H.-J. Hey, Auslegeschrift DE 25 40 972 (17 March 1977) Hoechst AG.

  21. T. Balg, Eur. Patent 0 003 624 B1 (1978) Stamicarbon B.V.

  22. Y.S. Park, Y.S. Lee and K.B. Yoon, J. Am. Chem. Soc. 115 (1993) 12220.

    Google Scholar 

  23. Y.S. Park, Y.S. Lee and K.B. Yoon, in: Zeolites and Related Microporous Materials: State of the Art 1994, Stud. Surf. Sci. Catal., Vol. 84, eds. J. Weitkamp, H.G. Karge, H. Pfeifer and W. Hölderich (Elsevier, Amsterdam, 1994) p. 901.

    Google Scholar 

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Meyer, U., Gorzawski, H. & Hölderich, W. Michael addition of ethyl acrylate and acetone over solid bases. Catalysis Letters 59, 201–206 (1999). https://doi.org/10.1023/A:1019020504961

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