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Ethylene Conversion over Catalysts Based on Solid Superacids and Heteropoly Acids

  • CHEMICAL KINETICS AND CATALYSIS
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Abstract

Catalytic properties of solid superacids (WO3/ZrO2 and SO4/ZrO2), and monolith and H-Beta zeolite-supported phosphotungstic heteropoly acid in gas-phase alkylation of benzene with ethylene to ethylbenzene and in the side reaction of ethylene oligomerization are studied. It was found that H-Beta zeolite had the highest activity and selectivity to ethylbenzene. The use of solid superacid (WO3/ZrO2) was shown to be more efficient in low-temperature oligomerization of ethylene.

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ACKNOWLEDGMENTS

This study was supported by the Russian Science Foundation (grant no. 14-50-00126).

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  1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia

    A. L. Tarasov

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  1. A. L. Tarasov
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Correspondence to A. L. Tarasov.

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Translated by A. Zeigarnik

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Tarasov, A.L. Ethylene Conversion over Catalysts Based on Solid Superacids and Heteropoly Acids. Russ. J. Phys. Chem. 92, 2139–2142 (2018). https://doi.org/10.1134/S0036024418110407

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