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A novel palladium complex catalyst for carbonylation of alkynes under mild conditions

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Abstract

Carbonylation of alkynes has been carried out using a catalyst system consisting of Pd(OAc)2, a monophosphine, p‐toluene sulphonic acid and semilabile anionic bidentate ligands such as pyridine or piperidine carboxylic acids. Turnover frequencies (TOF) upto 3500 h−1 and 98% selectivity to 2‐substituted 2‐propenoic acid/ester have been achieved under mild CO pressures of 1–3 atm at 373 K.

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Authors and Affiliations

  1. Homogeneous Catalysis Division, National Chemical Laboratory, Pune, 411 008, India

    S. Jayasree, A. Seayad, S.P. Gupte & R.V. Chaudhari

Authors
  1. S. Jayasree
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  2. A. Seayad
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  3. S.P. Gupte
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  4. R.V. Chaudhari
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Jayasree, S., Seayad, A., Gupte, S. et al. A novel palladium complex catalyst for carbonylation of alkynes under mild conditions. Catalysis Letters 58, 213–216 (1999). https://doi.org/10.1023/A:1019002606353

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