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Synthesis and characterization of new precursors to nearly stoichiometric SiC ceramics: Part 1 The copolymer route

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Abstract

Organosilicon polymers with a (C/Si (atomic ratio)<1.28) exhibiting Si–Si and Si–CH2–Si linkages in their backbone have been prepared and characterized by multinuclear magnetic resonance and infrared spectroscopies, size exclusion chromatography and thermogravimetric analysis. These precursors give SiC ceramics with a C/Si (atomic ratio)≈1.14 and a relatively low oxygen content (between 1.5–3 at %).

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Authors and Affiliations

  1. Laboratoire de Chimie Organique et Organometallique, URA 35 CNRS-UB1, Universite de Bordeaux-I, 351 Cours de la Liberation, 33405, Talence, France

    A. TAZI HEMIDA, M BIROT, J. P PILLOT & J DUNOGUES

  2. Laboratoire des Composites Thermostructuraux, UMR 47 CNRS-SEP-UB1, Domaine Universitaire, 3 Allee de la Boetie, 33600, Pessac, France

    R PAILLER

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  1. A. TAZI HEMIDA
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  2. M BIROT
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  4. J DUNOGUES
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  5. R PAILLER
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HEMIDA, A.T., BIROT, M., PILLOT, J.P. et al. Synthesis and characterization of new precursors to nearly stoichiometric SiC ceramics: Part 1 The copolymer route. Journal of Materials Science 32, 3475–3483 (1997). https://doi.org/10.1023/A:1018637204036

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