Effects of the integrity of silicon thin films on the electrical characteristics of thin dielectric ONO film

Abstract

Capacitors with two kinds of lower electrodes were fabricated and their effects evaluated on the electrical characteristics of oxide–nitride–oxide (ONO) film. One of the electrodes was made of amorphous silicon film chemically deposited using a gas mixture of Si2H6–PH3; the other was made of poly-Si film deposited by SiH4 decomposition and doped by As+ ion implantation. The ONO thin dielectric layer was composed of natural oxide, CVD silicon nitride and thermal oxide formed on the silicon nitride. The capacitance, the leakage current, the dielectric breakdown field and the time-dependent dielectric breakdown (TDDB) were tested to evaluate the electrical properties of the capacitors. The leakage current and the dielectric breakdown voltage showed similar values between the two capacitors, whereas the TDDB under negative bias showed a great difference. This indicates that, with respect to electrical properties, the integrity of the oxide grown on the in situ P-doped amorphous silicon is better than the oxide grown on the As+ ion-implanted poly-Si. What is more, phosphorus in the amorphous silicon did not lead to any problems with junction depth, even after post heat treatment at 950°C.