Abstract
Superfine Y-TZP powders of high purity were prepared by using clean-room facilities. The effects of several kinds of minute or small amounts of additives on the densification and microstructural development of the Y-TZP powder were investigated. It was found that ≤1 wt% ferric or calcium oxides did not affect the densification of the Y-TZP powder compacts, while the addition of sodium oxides retarded the densification and that of copper oxide accelerated it, and these effects are most obvious at an additive level of 1 wt%. The retardation of the densification by sodium oxide was found to result from the agglomeration effect of the powder, and the formation of the eutectic liquid phase between zirconia and copper oxides promoted the densification and grain growth during sintering of copper oxide-doped powder. In addition, sodium and copper oxides both destabilize the tetragonal Y-TZP and lead to the formation of monoclinic phase.
Similar content being viewed by others
References
R. L. Coble, J. Appl. Phys. 32 (1961) 793.
S. L. Bennison and M. P. Harmer, in “Ceramic Transactions”, Vol. 7, “Sintering Advanced Ceramics”, edited by C. A. Handwerker, J. E. Blendel and W. A. Kaysser (American Ceramic Society, Westerville, OH, 1990) pp. 13–49.
K. A. Berry and M. P. Harmer, J. Am. Ceram. Soc. 69 (1986) 143.
S. I. Bae and S. Baik, ibid. 77 (1994) 3499.
R. S. Garvie, R. H. J. Hannik and R. T. Pascoe, Nature(Lond.) 258 (1975) 703.
A. H. Heuer and L. W. Hobbs (eds), “Advances in Ceramics”, Vol. 3, “Science and Technology of Zirconia, I” (American Ceramic Society, Columbus, OH, 1981).
N. Cluassen, M. Ruehle and A. H. Heuer (eds), “Advances in Ceramics”, Vol. 12, “Science and Technology of Zirconia, II” (American Ceramic Society, Columbus, OH, 1984).
S. Somiya, N. Yamamoto and H. Hanagida (eds), “Advances in Ceramics”, Vol. 24, “Science and Technology of Zirconia, III” (American Ceramic Society, Columbus, OH, 1988).
E. M. Levin and M. F. Mamurdie (eds), “Phase Diagrams for Ceramics”, Vol. III “1975 Supplement”, no. 4533, (American Ceramic Society, Columbus, OH, 1975) p. 214.
R. C. Weast (ed), “Handbook of Physical Chemistry”, 59th Edn (CRC, West Palm Beach, 1978) p. B–167.
M. Miyayama and R. J. Yanagida, J. Am. Ceram. Soc. 67 (1984) C–194.
A. J.A. Winnubst and A. J. Burggraaf, in “Advances in Ceramics”, Vol. 24, “Science and Technology of Zirconia III”, edited by S. Somiya, N. Yamamoto and H. Hanagida (American Ceramic Society, Columbus, OH, 1988) p. 39.
E. M. Levin, C. R. Robbins and M. F. Mamurdie (eds), “Phase Diagrams for Ceramics”, Vol. II, “1969 Supplement”, no. 2145, (American Ceramic Society, Columbus, OH, 1969) p. 33.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
SHI, J.L., YEN, T.S. & SCHUBERT, H. Effect of small amounts of additives on the sintering of high-purity Y-TZP. Journal of Materials Science 32, 1341–1346 (1997). https://doi.org/10.1023/A:1018516925649
Published:
Issue Date:
DOI: https://doi.org/10.1023/A:1018516925649