Abstract
The crystal and molecular structures of [Mn(mep)2- (NCS)2] ({ {mep}}=4-methoxy-2-(5-methoxy-3-methyl-1H-pyrazol-1-yl)-6-methylpyrimidine) have been determined by X-ray crystallography. The crystal structure of the title compound is built up of isolated [Mn(mep)2(NCS)2] molecules with the stereochemistry of a distorted octahedron for the MnN6 chromophore. The e.p.r. (Q-band) data are in agreement with the structural data.
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E. Tabaka, R. Kodama, Y. Tanaka, R. Dohmori, H. Tachizanawa and P. Naito, Chem. Pharm. Bull., 18, 1900 (1970).
M. C. Molla, J. García-Lozano, J. Borrà s, C. Foces-Foces, F.H. Cano and M. Martínez-Ripoll, Transition Met. Chem., 10, 460 (1985).
L. Soto, J. García-Lozano, E. Escrivà, J.-P. Legros, J.-P. Tuchagues, F. Dahan and A. Fuertes, Inorg. Chem., 28, 3378 (1989).
M. Benetó, L. Soto, J. García-Lozano, E. Escrivà, J.-P. Legros, and F. Dahan, J. Chem. Soc., Dalton Trans., 1057 s(1991).
L. Soto, J. García-Lozano, E. Escrivà M. Benetó, F. Dahan, J.-P. Tuchagues and J.-P. Legros, J. Chem. Soc. Dalton Trans., 2619 (1991).
L. Soto, J. García-Lozano, E. Escrivà and J.-P. Legros, Polyhedron, 6, 647 (1992).
M. Benetó, J. García-Lozano, L. Soto, J. V. Folgado and E. Escrivà, Polyhedron, 8, 1523 (1992).
M. Benetó, J. García-Lozano and E. Escrivà, J. Coord. Chem., 200, 141 (1989)
A. Altomare, M. C. Burla, M. Camalli, G. Cascarano, G. Giacovazzo, A. Guagliardi and G. Polidori, SIR 92, J. Appl. Cryst., 27, 435 (1994).
J. M. Stewart, P. A. Machin, C. W. Dickinson, H. L. Ammon, H. Heck and H. Flack, The XRAY76 System, Computer Science Center, University of Maryland, College Park, Maryland, 1976.
M. Martínez-Ripoll and F. H. CanoPESOS: A Computer Program for the Automatic Treatment of Weighting SchemesInstituto Rocasolano, CSIC Madrid, 1975.
International Tables for X-Ray Crystallography, Kynoch Press, Birmingham, England, 1974, Vol. 4, p. 72.
A. M. Golub, H. Köhler and V. V. Skopenko, Chemistry of Pseudohalides, Elsevier, Amsterdam, 1986.
J. L. Burmeister, Coord. Chem. Rev., 105, 77 (1990).
B. W. Dockum, G. A. Eisman, E. H. Witten and W. M. Reiff, Inorg. Chem., 22, 151 (1983).
B. J. Hathaway, Struct. Bonding, 57, 55 (1984).
E. L. Muetterties and L. J. Guggenberger, J. Am. Chem. Soc., 96, 1748 (1974).
R. D. Dowsing and F. J. Gibson, J. Chem. Phys., 50, 294 (1969).
R. D. Dowsing, F. J. Gibson, M. Goodgame and P. J. Hayward, J. Chem Soc., (A), 187 (1969).
R. D. Dowsing, F. J. Gibson, M. Goodgame and P. J. Hayward, J. Chem Soc., (A), 1133 (1970).
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Garci´a-Lozano, J., Server-Carrio´, J., Molla, M.C. et al. Monomeric cis-isothiocyanato complexes. Crystal and molecular structure of [Mn(mep)2(NCS)2] (mep=4-methoxy-2-(5-methoxy- 3-methyl-1H-pyrazol-1-yl)-6-methylpyrimidine). Transition Metal Chemistry 22, 161–163 (1997). https://doi.org/10.1023/A:1018471214956
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DOI: https://doi.org/10.1023/A:1018471214956