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Synthesis and Spectral Properties of Unsymmetrically Substituted Mn(II) and Mn(III) Octaethylporphyrins

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Abstract

5-Mononitro-2,3,7,8,12,13,17,18-octaethylporphyrin, 5,10,15-trinitro-2,3,7,8,12,13,17,18-octaethylporphyrin, and their Cd(II) complexes were synthesized. The coordination reactions of 2,3,7,8,12,13,17,18-octaethylporphyrin and its mono- and trinitro-substituted derivatives and the metal-exchange reactions of the synthesized Cd(II) octaethylporphyrin complexes with Mn(II) chloride in DMF were investigated by spectrophotometry. The corresponding Mn(II) and Mn(III) porphyrins were obtained and identified. The kinetic parameters of the studied reactions were determined.

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ACKNOWLEDGMENTS

The work was performed using the equipment of the “Upper Vologa Regional Center for Physical and Chemical Research” Center for Collective Use.

Funding

The work was financially supported by the Russian Foundation for Basic Research: project no. 19-03-00078_A [synthesis of porphyrin ligands and their Cd(II), Mn(II), and Mn(III) complexes] and project no. 1843370001_r-a [study of the metal-exchange reaction of the Cd(II) complexes of the synthesized porphyrins with Mn(II) chloride].

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Authors and Affiliations

  1. Krestov Institute of Solution Chemistry, Russian Academy of Sciences, 153045, Ivanovo, Russia

    S. V. Zvezdina, N. V. Chizhova & N. Zh. Mamardashvili

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  1. S. V. Zvezdina
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  2. N. V. Chizhova
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  3. N. Zh. Mamardashvili
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Correspondence to S. V. Zvezdina.

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Zvezdina, S.V., Chizhova, N.V. & Mamardashvili, N.Z. Synthesis and Spectral Properties of Unsymmetrically Substituted Mn(II) and Mn(III) Octaethylporphyrins. Russ J Org Chem 56, 1374–1382 (2020). https://doi.org/10.1134/S1070428020080072

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