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Ruthenium dioxide films on titanium wire electrodesby spray pyrolysis: preparation and electrochemicalcharacterization

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Abstract

A device for the preparation of thick and uniform films of ruthenium dioxide on titanium wires by the spray pyrolysis technique has been developed. The details of the apparatus, as well as the operation conditions, are described. The electrodes obtained were characterized by X-ray diffraction analysis, scanning electron microscopy and cyclic voltammetry. Their electrocatalytic activity for chlorine evolution were also evaluated, as well as their stability through an accelerated test of service life.

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References

  1. S. Trasatti and G. Lodi, in `Electrodes of conductive metallic oxides' (edited by S. Trasatti), Part A, Elsevier, Amsterdam (1980), chapter 7.

    Google Scholar 

  2. R.R. Chamberlin and J. J. Skarman, J. Electrochem. Soc. 113 (1966) 86.

    Google Scholar 

  3. J. C. Viguié and J. Spitz, ibid. 122 (1975) 585.

    Google Scholar 

  4. J. F. Koenig, A. Sehili, M. Hamdani and P. Chartier, J. Appl. Electrochem. 14 (1984) 241.

    Google Scholar 

  5. M. Hamdani, J. F. Koenig and P. Chartier, ibid. 18 (1988) 561.

    Google Scholar 

  6. B. Correa Lozano, C. H. Comninellis and A. De Battisti, ibid. 26 (1996) 83.

    Google Scholar 

  7. J. Brunaux, H. Cachet, M. Froment and A. Messad, Electrochim. Acta 39 (1994) 1251.

    Google Scholar 

  8. A. Restovic, G. Poillerat, J.F. Koenig, P. Chartier and J. L. Gautier, Thin Solid Films 199 (1991) 139.

    Google Scholar 

  9. G. H. Ayres and F. Young, Anal. Chem. 22 (1950) 1277.

    Google Scholar 

  10. T. Loucka, J. Appl. Electrochem. 7 (1977) 211.

    Google Scholar 

  11. C. Iwakura, K. Irao and H. Tamura, Electrochim. Acta 22 (1977) 335.

    Google Scholar 

  12. M. D. Spasojevic, N. V. Krstajic and M. M. Jaksic, J. Res. Inst. Catalisis Hokkaido Univ. 31 (1983) 213.

    Google Scholar 

  13. F. Hine, M. Yasuda and T. Yoshida, J. Electrochem. Soc. 124 (1977) 500.

    Google Scholar 

  14. ASTM X-ray Powder Diffraction Files, 21-1172 and 40-1290.

  15. F. Hine, M. Yasuda, T. Noda, T. Yoshida and J. Okuda, J. Electrochem. Soc. 126 (1979) 1439.

    Google Scholar 

  16. G. Jang and K. Rajeshwar, J. Electrochem. Soc. 134 (1987) 1830.

    Google Scholar 

  17. V. V. Losev, Elektrokhimiya 17 (1981) 733.

    Google Scholar 

  18. M. R. Gennero de Chialvo and A. C. Chialvo, Electrochim. Acta 38 (1993) 2247.

    Google Scholar 

  19. Idem, ibid. 35 (1990) 437.

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Authors and Affiliations

  1. Programa de Electroqui´mica Aplicada e Ingenieri´a Electroqui´mica (PRELINE), Facultad de Ingenieri´a Qui´mica, Universidad Nacional del Litoral, Santiago del Estero 2829, 3000, Santa Fe, Argentina

    J. L. FERNA´NDEZ , M. R. GENNERO DE CHIALVO  & A. C. CHIALVO

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  1. J. L. FERNA´NDEZ
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  2. M. R. GENNERO DE CHIALVO
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  3. A. C. CHIALVO
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FERNA´NDEZ , J.L., CHIALVO , M.R.G.D. & CHIALVO , A.C. Ruthenium dioxide films on titanium wire electrodesby spray pyrolysis: preparation and electrochemicalcharacterization. Journal of Applied Electrochemistry 27, 1323–1327 (1997). https://doi.org/10.1023/A:1018408725898

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  • DOI: https://doi.org/10.1023/A:1018408725898

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