Abstract
Complexes of CoII and NiII with new Schiff bases derived from 4-amino-5-sulfanyl-1,2,4-triazoles and glyoxal, biacetyl or benzil have been prepared. All have the stoichiometry ML(H2O)2, with L coordination via the two imine nitrogens and two thiolato sulfurs in an overall octahedral geometry.
Some of the complexes were screened for their antibacterial and antifungal activity, and one representative CoII complex was evaluated for oxytocic activity.
Similar content being viewed by others
References
F. Blau, Ber, 21, 1007 (1888); Monatsh. Chem., 19, 647 (1898).
H. M. Fisher and R. Cartstoufer, Inorg. Chem., 5, 1172 (1966).
G. Mukerjee, S. N. Poddar and K. Day, Transition Met. Chem., 12, 323 (1987).
S. A. Patil, B. M. Badiger, S. M. Kudari and V. H. Kulkarni, Transition Met. Chem., 8, 238 (1983).
B. M. Badiger, S. A. Patil, S. M. Kudari and V. H. Kulkarni, Rev. Roum. Chim., 31, 849 (1986).
A. Y. Naik, S. D. Angadi and V. H. Kulkarni, Oriental J. Chem., 10, 23 (1994).
G. Mukerjee, S. M. Poddar and K. Dey, Transition Met. Chem., 12, 323 (1987).
K. Dey, S. Ray, P. K. Bhattacharya, A. Gangopdhyaay, K. K. Bhasin and R. D. Verma, J. Indian Chem. Soc., 62, 809 (1985) and refs cited therein.
M. S. Yadawe and S. A. Patil, Indian J. Heterocycl. Chem., 2, 41 (1992).
K. S. Dhaka, Jag Mohan, V. K. Chadha and H. K. Pujari, Indian J. Chem., 12B, 288 (1974).
A. I. Vogel, A Text Book of Quantitative Inorganic Analysis, 34th Edit. ELBS, London, 1962.
N. K. Singh, S. Agarwal and R. C. Agarwal, Indian J. Chem., 21, 973 (1982).
L. J. Bellamy, IR Spectra of Complex Molecules, Wiley, New York, 1958.
R. V. Gadag and M. R. Gajendragad, Indian J. Chem., 16A, 703 (1978); Talanta, 25, 418 (1978).
K. Nakamoto, IR and Raman Spectra of Inorganic and Coordination Complexes, 3rd Edit. Wiley, New York, 1978 p. 213.
P. Gluvchinsky, G. M. Mockler and E. Sinn, Spectrochim. Acta, Part A 33, 1073 (1972).
R. V. Gadag and M. R. Gajendragad, Indian J. Chem., 19A, 705 (1980).
F. A. Cotton and G. W. Wilkinson, Advanced Inorganic Chemistry, Wiley, New Delhi, 1969.
A. B. P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, 1968.
N. Saha and K. M. Datta, Indian J. Chem., 21A, 180 (1982).
N. Saha and N. C. Gayen, J. Indian Chem. Soc., 60, 317 (1983).
C. J. Ballhausen, Introduction to Ligand Field Theory, McGraw-Hill, New York, 1962.
B. M. Figgis, Introduction to Ligand Fields Interscience, New York, 1967.
M. B. Singh and J. Singh, J. Inorg. Nucl. Chem., 41, 1384 (1979).
A. K. Sengupta, O. P. Bajaj and U. Chandra, J. Indian Chem. Soc., 55, 962 (1978).
H. Singh, L. D. S. Yadav and P. K. Bhattacharya, J. Indian Chem., Soc. 56, 1013 (1979) and refs cited therein.
S. Giri, H. Singh, L. D. S. Yadav and R. K. Khare, J. Indian Chem. Soc., 55, 168 (1978).
G. Tanara, Jpn. Kokai, 973, 7495 (1974); Chem. Abstr., 82, 156320h (1975).
S. A. Patil, B. M. Badiger, S. M. Kudari and V. H. Kulkarni, J. Indian Chem. Soc., 61, 713 (1984).
S. A. Patil and V. H. Kulkarni, Acta Chim. Hungary, 118, 3 (1985).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Yadawe, M.S., Patil, S.A. Synthesis, characterization and biological studies of cobalt(II) and nickel(II) complexes with new Schiff bases. Transition Metal Chemistry 22, 220–224 (1997). https://doi.org/10.1023/A:1018400121316
Published:
Issue Date:
DOI: https://doi.org/10.1023/A:1018400121316