Abstract
Structural transformations and microstructural characterisation of Sm2Co17 alloys containing Fe, Cu and Zr at different stages of thermal processing have been investigated by X-ray diffraction, optical, scanning electron and transmission electron microscopes. Solution treated samples consist of a mixture of hexagonal TbCu7 (1:7 H) and rhombohedral Th2Zn17 (2:17 R) structure types of 2:17 phase. After isothermal aging, TbCu7 + Th2Zn17 structures transform into Th2Zn17 type structure with precipitation of Cu-rich hexagonal SmCo5 (1:5 H) and Zr-rich platelet phases. In addition to the main phases, a soft magnetic phase of composition Zr6(FeCo)23 is formed in alloys containing higher Zr composition. Isothermal aging studies reveal that magnetic properties show a peak value when aged at 1108–1123 K for 10 h. TEM studies show cellular precipitate structure with cell interiors having 2:17 R structure, while the fully coherent cell boundaries have the 1:5 H structure. Zr-rich platelets which run across many cells and cell boundaries were found to have 1:7 H structure.
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Gopalan, R., Muraleedharan, K., Sastry, T.S.R.K. et al. Studies on structural transformation and magnetic properties in Sm2Co17 type alloys. Journal of Materials Science 36, 4117–4123 (2001). https://doi.org/10.1023/A:1017992132473
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DOI: https://doi.org/10.1023/A:1017992132473