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Decomposition of H2O2 by Fe Imidazole or Fe Histidine Complexes Immobilized in Porous Matrices

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Abstract

Fe(III) imidazole or histidine complexes were immobilized in porous matrices (montmorillonite and MCM-41) via two methods (introduction of preformed complex and complex formation within the ion-exchanged host substances). It was found that immobilization was successful only by the latter method. Immobilization increased the catalytic activity and catalyst life time in the decomposition reactions of hydrogen peroxide relative to the matrix-free complexes. The immobilized materials were characterized by various physicochemical methods.

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Authors and Affiliations

  1. Department of Applied and Environmental Chemistry, University of Szeged, Rerrich B. tér 1, H-6720, Szeged, Hungary

    Klara Hernadi, Mária Bóka & Imre Kiricsi

  2. Department of Organic Chemistry, University of Szeged, Dóm tér 8, H-6720, Szeged, Hungary

    István Pálinkó

Authors
  1. Klara Hernadi
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  2. István Pálinkó
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  3. Mária Bóka
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  4. Imre Kiricsi
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Correspondence to Klara Hernadi.

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Hernadi, K., Pálinkó, I., Bóka, M. et al. Decomposition of H2O2 by Fe Imidazole or Fe Histidine Complexes Immobilized in Porous Matrices. Reaction Kinetics and Catalysis Letters 74, 195–200 (2001). https://doi.org/10.1023/A:1017912405772

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