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Using Immobilized Hybrid Composites Based on Mixed Polyoxometalates As Catalysts for the Oxidation of Heteroatomic Compounds

  • CHEMICAL KINETICS AND CATALYSIS
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Abstract

A set of silica gel-immobilized compounds is synthesized that consists of ethylimidazole cations and anions of phosphotungstic acid (lacunar (PW11) or mixed (PW11M), where M = Zn, Ni, Cu, Co, Mn). The composition and textural characteristics of the compounds are determined by physicochemical means (IR spectroscopy, XPS, SEM/EDX, adsorption). The synthesized heterogeneous composites are active in the oxidation of sulfur- and nitrogen-containing components of petroleum feedstocks with hydrogen peroxide. A comparative analysis is performed of the samples’ catalytic properties in the oxidation of both individual substrates (thiophene, dibenzothiophene, methyl phenyl sulfide, pyridine) and their mixtures.

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Funding

This work was performed within the framework of the State Assignment to the Lomonosov Moscow State University (project no. AAAA-A21-121011590090-7) on equipment purchased as part of the Program for the Development of Moscow State University.

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Authors and Affiliations

  1. Faculty of Chemistry, Moscow State University, 119991, Moscow, Russia

    V. M. Zelikman, K. I. Maslakov, I. A. Ivanin & I. G. Tarkhanova

Authors
  1. V. M. Zelikman
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  2. K. I. Maslakov
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  3. I. A. Ivanin
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  4. I. G. Tarkhanova
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Corresponding author

Correspondence to I. G. Tarkhanova.

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The authors declare that they have no conflict of interest.

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Translated by M. Timoshinina

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Zelikman, V.M., Maslakov, K.I., Ivanin, I.A. et al. Using Immobilized Hybrid Composites Based on Mixed Polyoxometalates As Catalysts for the Oxidation of Heteroatomic Compounds. Russ. J. Phys. Chem. 97, 1871–1879 (2023). https://doi.org/10.1134/S0036024423090273

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  • DOI: https://doi.org/10.1134/S0036024423090273

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