Abstract
The reactions of substituted 5H-imidazo[1,2-b]-1,2,4-triazepin-4-ones and -thiones with bromine and N-bromosuccinimide have been studied. Derivatives of 3- and 8-bromo-, 3,8-dibromoimidazo[1,2-b]-1,2,4-triazepine and 5H-2-bromomethyl-3-methyl-7,8-diphenylimidazo[1,2-b]-1,2,4-triazepin-4-one are formed, depending on the degree of substitution, the nature of the brominating agent, and the reaction conditions.
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V. P. Kruglenko, N. S. Patalakha, P. V. Kurapov, N. A. Klyuev, V. A. Idzikovskii, I. I. Grandberg, and M. V. Povstyanoi, Khim. Geterotsikl. Soedin., 694 (1985).
V. P. Kruglenko, V. A. Idzikovskii, N. A. Klyuev, and M. V. Povstyanoi, Khim. Geterotsikl. Soedin., 386 (1988).
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Kruglenko, V.P. Bromination of Substituted 5H-Imidazo[1,2-b]-1,2,4-triazepin-4-ones and -thiones. Chemistry of Heterocyclic Compounds 37, 500–503 (2001). https://doi.org/10.1023/A:1017664207584
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DOI: https://doi.org/10.1023/A:1017664207584