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IR Spectroscopic Study of Chemical Transformations upon Irradiation of the Poly(vinyl chloride)–Triallyl Cyanurate System

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Abstract

Chemical transformations resulting from irradiation of the poly(vinyl chloride) (PVC)–triallyl cyanurate (TAC) system were studied by IR spectroscopy. It was shown that crosslinking was accompanied by scission of the network structure formed in the initial dose range, and the scission process occurred even at small irradiation doses. The scission is assumed to be localized at the interface boundary between PVC and poly(iso-TAC) or poly(TAC).

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Authors and Affiliations

  1. Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, ul. Profsoyuznaya 70, Moscow, 117393, Russia

    N. A. Shmakova

  2. Karpov Institute of Physical Chemistry, Russian Federal Research Center, ul. Vorontsovo pole 10, Moscow, 103064, Russia

    V. I. Feldman & F. F. Sukhov

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  1. N. A. Shmakova
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  2. V. I. Feldman
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  3. F. F. Sukhov
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Shmakova, N.A., Feldman, V.I. & Sukhov, F.F. IR Spectroscopic Study of Chemical Transformations upon Irradiation of the Poly(vinyl chloride)–Triallyl Cyanurate System. High Energy Chemistry 35, 224–228 (2001). https://doi.org/10.1023/A:1017628410368

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