Skip to main content
SpringerLink
Log in

Intramolecular Crosslinking of Polyvinylidene Fluoride by Homogeneous Solution Irradiation

  • GENERAL ASPECTS
  • Published:
High Energy Chemistry Aims and scope Submit manuscript

Abstract

Intramolecular crosslinking of polyvinylidene fluoride (PVDF) was observed to have occurred when the PVDF homogeneous solution was subject to γ-ray irradiation, which was confirmed by characterization of PVDF before and after irradiation via FTIR, the thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), gel permeation chromatography (GPC), viscosity measurement and small-angle X-ray scattering (SAXS). This constitutes a contrast to the frequent occurrence of intermolecular crosslinking that takes place when PVDF is irradiated in a solid state. Such a finding increases our understanding of the radiation effects of polymers. Based on the experimental results, a possible crosslinking mechanism is also proposed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. Yu, S., Mech. Compos. Mater., 1972, vol. 2, p. 120.

    Google Scholar 

  2. Azwa, Z.N., Yousif, B.F., Manalo, A.C., and Karunasena, W., Mater. Des., 2013, vol. 47, p. 424.

    Article  CAS  Google Scholar 

  3. Manas, D., Hribova, M., Manas, M., Ovsik, M., Stanek, M., and Samek, D., Thin Solid Films, 2013, vol. 530, p. 49.

    Article  CAS  Google Scholar 

  4. Sonnier, R., Caro-Bretelle, A.S., Dumazert, L., Longerey, M., and Otazaghine, B., Radial. Phys. Chem., 2015, vol. 106, p. 278.

    Article  CAS  Google Scholar 

  5. Shaffer, S., Yang, K., Vargas, J., Di Prima, M.A., and Voit, W., Polymer, 2014, vol. 55, p. 5969.

    Article  CAS  Google Scholar 

  6. Cleland, M.R., Parks, L.A., and Cheng, S., Methods Phys. Res., Sect. B., 2003, vol. 208, p. 66.

    CAS  Google Scholar 

  7. Clough, R.L., Methods Phys. Res., Sect. B., 2001, vol. 185, p. 8.

    CAS  Google Scholar 

  8. Silva, C.D.S., Pereira, D.H., and Custodio, R., J. Chem. Phys., 2016, vol. 144, p. 1079.

    Article  Google Scholar 

  9. Liu, F., Hashim, N.A., Liu, Y., Abed, M.R., and Li, K., J. Membr. Sci., 2011, vol. 375, p. 1.

    Article  CAS  Google Scholar 

  10. Sabira, K., Saheeda, P., and Anila, E.I., J. Lumin., 2017, vol. 188, p. 136.

    Article  Google Scholar 

  11. Qing, Y., Yang, C., Yu, N., Shang, Y., Sun, Y., Wang, L., and Liu, C., Chem. Eng. J., 2016, vol. 290, p. 37.

    Article  CAS  Google Scholar 

  12. Bhingardive, V., Sharma, M., Suwas, S., Madras, G., and Bose, S., RSC Adv., 2015, vol. 5, p. 359.

    Google Scholar 

  13. Ivanov, V.S., Migunova, I.I., and Mikhailov, A.I., Radial. Phys. Chem., 1991, vol. 37, p. 119.

    CAS  Google Scholar 

  14. Lyons, B. J., Radial. Phys. Chem., 1995, vol. 45, p. 159.

    Article  CAS  Google Scholar 

  15. Forsythe, J.S., and Hill, D.J., Prog. Polym. Sci., 2000, vol. 25, p. 101.

    Article  CAS  Google Scholar 

  16. Timmerman, R., and Greyson, W., J. Appl. Polym. Sci., 1962, vol. 6, p. 456.

    Article  CAS  Google Scholar 

  17. Rosenbearg, Y., Siegmann, A., Narkis, M., and Shkolnik, S., J. Appl. Polym. Sci., 1991, vol. 43, p. 535.

    Article  Google Scholar 

  18. Kabanov, V.Y., Feldman, V.I., and Ershov, B.G., High Energ. Chem., 2009, vol. 2, p. 76.

    Google Scholar 

  19. Makuuchi, K., Asano, M., and Abe, T., J. Polym. Sci., Part A: Polym. Chem., 1976, vol. 14, p. 617.

    CAS  Google Scholar 

  20. Zhudi, Z., Wenxue, Y., and Xinfang, C., Radial. Phys. Chem., 2002, vol. 65, p. 173.

    Article  Google Scholar 

  21. Zhong, X.,Yu, L., Zhao, W., Zhang, Y., and Sun, J., Polym. Degrad. Stab., 1993, vol. 39, p. 399.

    Article  CAS  Google Scholar 

  22. Kulkarni, S.S. and Khadke, U.V., J. Mater. Sci., 2016, vol. 2, p. 213.

    Google Scholar 

  23. Makuuchi, K., Asano, M., and Abe, T., Nippon Kagaku Kaishi., 1975, vol. 75, p. 728.

    Article  Google Scholar 

  24. Chen, P., Hou, J., and Lu, X., J. Radiat. Res., 2011, vol. 29, p. 134.

    CAS  Google Scholar 

  25. Lanceros-Mendez, S., Mano, J.F., Costa, A.M., and Schmidt, V.H., J. Macromol. Sci., Part B., 2001, vol. 40, p. 517.

    Google Scholar 

  26. Ross, G.J., Watts, J.F., Hill, M.P., and Morrissey, P., Polymer, 2000, vol. 41, p. 1685.

    Article  CAS  Google Scholar 

  27. Nasef, M. and Dahlan, K.Z., Nucl. Instrum. Methods Phys. Res., Sect. B., 2003, vol. 201, p. 604.

    CAS  Google Scholar 

  28. Medeiros, A.S., Gual, M.R., Pereira, C., and Faria, L.O., Radial. Phys. Chem., 2015, vol. 116, p. 345.

    Article  CAS  Google Scholar 

  29. Potschka, M., Anal. Biochem., 1987, vol. 162, p. 47.

    Article  CAS  Google Scholar 

  30. Gebben, B., van den Berg, H.W.A., Bargeman, D., and Smolders, C.A., Polymer., 1985, vol. 26, p. 1737.

    Article  CAS  Google Scholar 

  31. Shah, S. C., Kopolow, S. L., and Smid, J., Polymer, 1980, vol. 21, p.188.

    Article  CAS  Google Scholar 

  32. Sim, A.Y.L., Lipfert, J., Herschlag, D., and Doniach, S., Phys. Rev. E: Stat. Phys., Plasmas, Fluids, Relat. Interdiscip. Top., 2012, vol. 86, p. 21.

    Article  Google Scholar 

  33. Feng, T., Zhongfeng, T., Hongjie, X., Jie, W., Guozhong, W., and Xiuhong, L., Polym. Compos., 2011, vol. 19, p. 439.

    Article  Google Scholar 

  34. Wisotzki, E.I., Tempesti, P., Fratini, E., and Mayr, S.G., Phys. Chem. Chem. Phys., 2017, vol. 19, p. 120.

    Article  Google Scholar 

  35. Berestycki, P., J. Stat. Phys., 2007, vol. 23, p. 220.

    Google Scholar 

  36. Liu, F., Polymer, 2007, vol. 48, p.291.

    Google Scholar 

Download references

Funding

This work was supported financially by the Science and technology research project of Chongqing Education Commission (Project no. KJQN202003103), the open projects of the CAS key laboratory of interfacial physics and technology (nos. CASKL-IPT2002 and CASKL-IPT2004), Gansu Natural Science Foundation (Project no. 20JR10RA778).

Author information

Authors and Affiliations

  1. School of Architecture and Materials, Chongqing College of Electronic Engineering, 401331, Chongqing, China

    K. Fan & H. Zeng

  2. Chongqing Key Laboratory of Green Synthesis and Applications, College of Chemistry, Chongqing Normal University, 401331, Chongqing, China

    C. Liu

  3. Shanghai Institute of Applied Physics, Chinese Academy of Sciences, 201800, Shanghai, China

    J. H. Li

Authors
  1. K. Fan
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. C. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. H. Zeng
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. H. Li
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to C. Liu or J. H. Li.

Ethics declarations

The authors declare no conflict of interest.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Fan, K., Liu, C., Zeng, H. et al. Intramolecular Crosslinking of Polyvinylidene Fluoride by Homogeneous Solution Irradiation. High Energy Chem 55, 436–441 (2021). https://doi.org/10.1134/S0018143921060059

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0018143921060059

Keywords:

Search

Navigation