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Electrochemical Template Synthesis of an Polyaniline Composite with Polymeric Perfluorinated Sulfo Cationite

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Abstract

Combining a tracer technique with electrochemical measurements offers a unique opportunity to study the mechanism of anodic synthesis of a composite based on an electron-conducting polymer (polyaniline) and a polymeric perfluorinated sulfo cationite (Nafion, MF-4SK). The composite formation involves two steps. First, the monomer (aniline) is intercalated into the solid-cationite matrix probably with the formation of a template phase, after which postintercalation polymerization of the template occurs.

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Authors and Affiliations

  1. Russian Academy of Sciences, Frumkin Institute of Electrochemistry, Leninskii pr. 31, Moscow, 117071, Russia

    N. M. Alpatova, V. N. Andreev & N. N. Belova

  2. Russian Academy of Sciences, Institute of Physical Chemistry, Leninskii pr. 31, Moscow, 117915, Russia

    A. I. Danilov, E. B. Molodkina & Yu. M. Polukarov

  3. Kuban State University, ul. Stavropol'skaya 149, Krasnodar, 350040, Russia

    N. P. Berezina

  4. Joint Stock Company Plastpolymer, St. Petersburg, Russia

    S. V. Timofeev & L. P. Bobrova

Authors
  1. N. M. Alpatova
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  2. V. N. Andreev
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  3. A. I. Danilov
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  4. E. B. Molodkina
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  5. Yu. M. Polukarov
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  6. N. P. Berezina
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  7. S. V. Timofeev
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  8. L. P. Bobrova
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  9. N. N. Belova
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Alpatova, N.M., Andreev, V.N., Danilov, A.I. et al. Electrochemical Template Synthesis of an Polyaniline Composite with Polymeric Perfluorinated Sulfo Cationite. Russian Journal of Electrochemistry 38, 913–918 (2002). https://doi.org/10.1023/A:1016830232216

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  • DOI: https://doi.org/10.1023/A:1016830232216

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