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Liquid Phase Selective Benzoylation of Chlorobenzene to 4,4′-Dichlorobenzophenone over Zeolite H-Beta

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Abstract

Selective formation of 4,4′-dichlorobenzophenone (>88%) at 19.8 wt% conversion level of 4-chlorobenzoylchloride (4-ClBC) and at 8.4×10−4 s−1mol−1 Al turnover frequency (TOF) of 4-chlorobenzoylchloride is reported for the first time in the benzoylation of chlorobenzene using 4-ClBC as benzoylating agent and zeolite H-beta as the catalyst.

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Authors and Affiliations

  1. Catalysis Division, National Chemical Laboratory, Pune, 411 008, India

    C. Venkatesan, T. Jaimol, A.V. Ramaswamy & A.P. Singh

  2. Laboratoire de Matériaux Catalytiques et Catalyse en Chimie Organique, UMR, 5618 CNRS-ENSCM, 8 Rue de l'Ecole Normale, 34296, Montpellier Cedex 5, France

    P. Moreau & A. Finiels

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  1. C. Venkatesan
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  2. T. Jaimol
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  3. P. Moreau
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  5. A.V. Ramaswamy
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Venkatesan, C., Jaimol, T., Moreau, P. et al. Liquid Phase Selective Benzoylation of Chlorobenzene to 4,4′-Dichlorobenzophenone over Zeolite H-Beta. Catalysis Letters 75, 119–123 (2001). https://doi.org/10.1023/A:1016771719956

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