Abstract
Information on the synthesis of a polyaniline film on platinum covered with a Nafion film is obtained. The effect of electrochemical conditions on the synthesis is studied. The relationship between these conditions and properties of obtained composite polyaniline–Nafion films is revealed. It is established that on platinum covered with a Nafion film in certain electrochemical conditions in a polyaniline solution there occurs the formation of a composite polyaniline–Nafion film. The polyaniline in the film mainly retains its individual properties. It is demonstrated that the mechanism of the synthesis of polyaniline in the composite film substantially differs from that in the case of the formation of a film on platinum.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Elektrokhimiya polimerov (The Electrochemistry of Polymers), Tarasevich, M.R. and Khrushcheva, E.I., Eds., Moscow: Nauka, 1990.
Koval'chuk, E.P., Aksiment'eva, E.I., and Tomilov, A.P., Elektrosintez polimerov na poverkhnosti metallov (Electrosynthesis of Polymers on the Surface of Metals), Moscow: Khimiya, 1991.
Electrochim. Acta, 1996, vol. 41, no. 11/12.
Penner, R.M. and Martin, C.R., J. Electrochem. Soc., 1986, vol.133, p. 310.
Diaz, A.F. and LaCroix, J.-C., Makromol. Chem., Macromol. Symp., 1987, vol. 8, p. 17.
Orata, D. and Buttry, D.A., J. Electrochem. Soc., 1988, vol. 257, p. 71.
Hirai, T., Kuwabata, S., and Yoneyama, H., J. Electrochem. Soc., 1988, vol. 135, p. 1132.
Fabrizio, M., Mengoli, G., Musiani, M., and Paolucci, F., J. Electroanal. Chem., 1999, vol. 300, p. 23.
Lai, E.K.W., Beattie, P.D., Orfino, F.P., et al., Electrochim. Acta, 1991, vol. 44, p. 2559.
Andreev, V.N., Elektrokhimiya, 1998, vol. 34, p. 1361.
Andreev, V.N., Elektrokhimiya, 1999, vol. 35, p. 824.
Andreev, V.N., Elektrokhimiya, 1999, vol. 35, p. 830.
Andreev, V.N., Elektrokhimiya, 2000, vol. 36, p. 379.
Kazarinov, V.E. and Andreev, V.N., Comprehensive Treatise of Electrochemistry, vol. 9: Electrodics, Yeager, E., Bockris, J.O'M., Conway, B.E., and Sarangapani, S., Eds., New York: Plenum, 1984, p. 393.
Khazova, O.A., Andreev, V.N., Vasil'ev, Yu.B., and Kazarinov, V.E., Elektrokhimiya, 1987, vol. 23, p. 1155.
Spitsyn, M.A. and Andreev, V.N., Elektrokhimiya, 1989, vol. 25, p. 1171.
Spitsyn, M.A., Maiorov, A.P., Andreev, V.N., and Kazarinov, V.E., Elektrokhimiya, 1990, vol. 26, p. 803.
Kazarinov, V.E., Andreev, V.N., Spytsin, M.A., and Shlepacov, A.V., Electrochim. Acta, 1990, vol. 35, p. 899.
Kazarinov, V.E., Andreev, V.N., Spytsin, M.A., and Mayorov, A.P., Electrochim. Acta, 1990, vol. 35, p. 1459.
Spitsyn, M.A., Shlepakov, A.V., and Andreev, V.N., Elektrokhimiya, 1991, vol. 27, p. 576.
Andreev, V.N., J. Electrochem. Soc., 1990, vol. 137, p. 165a.
Andreev, V.N. and Maiorov, A.P., Elektrokhimiya, 1993, vol. 29, p. 282.
Spitsyn, M.A., Andreev, V.N., and Kazarinov, V.E., Elektrokhimiya, 1995, vol. 31, p. 1182.
Andreev, V.N., Spitsyn, M.A., and Kazarinov, V.E., Elektrokhimiya, 1996, vol. 32, p. 1417.
Kazarinov, V.E., Andreev, V.N., and Spytsin, M.A., Electrochim. Acta, 1996, vol. 41, p. 1757.
Michaelson, J., Mcevoy, J., and Kuramoto, N., React. Polym., 1992, vol. 17, p. 197.
Inzelt, G., Horanyi, G., and Chambers, J.Q., Electrochim. Acta, 1987, vol. 32, p. 757.
Inzelt, G. and Horanyi, G., Electrochim. Acta, 1990, vol. 35, p. 27.
Kazarinov, V.E. and Andreev, V.N., Elektrokhimiya, 1974, vol. 10, p. 196.
Kazarinov, V.E. and Andreev, V.N., Elektrokhimiya, 1974, vol. 10, p. 205.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Andreev, V.N. Synthesis and Properties of Composite Polyaniline–Nafion Films on Platinum. Russian Journal of Electrochemistry 37, 605–611 (2001). https://doi.org/10.1023/A:1016618601532
Issue Date:
DOI: https://doi.org/10.1023/A:1016618601532