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Non-catalytic liquid phase oxidation of alkenes with nitrous oxide. 1. Oxidation of cyclohexene to cyclohexanone

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Abstract

A very efficient way of alkenes oxidation to carbonyl compounds is discovered. It is based on remarkable ability of nitrous oxide to interact directly with the double C=C bonds of liquid alkene and to transfer its oxygen, without catalyst aid, to unsaturated carbon atom with nearly 100% selectivity. This oxidation method can be applied to a wide range of organic compounds including aliphatic, cyclic, heterocyclic alkenes and their numerous derivatives.

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Authors and Affiliations

  1. Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia

    Gennady I. Panov, Konstantin A. Dubkov, Evgeny V. Starokon & Valentin N. Parmon

Authors
  1. Gennady I. Panov
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  2. Konstantin A. Dubkov
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  3. Evgeny V. Starokon
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  4. Valentin N. Parmon
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Panov, G.I., Dubkov, K.A., Starokon, E.V. et al. Non-catalytic liquid phase oxidation of alkenes with nitrous oxide. 1. Oxidation of cyclohexene to cyclohexanone. Reaction Kinetics and Catalysis Letters 76, 401–406 (2002). https://doi.org/10.1023/A:1016564818065

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  • DOI: https://doi.org/10.1023/A:1016564818065

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