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Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media

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Abstract

For the first time the reactions of radical nitration of alkenes and oxiranes with nitrogen dioxide in the liquid and supercritical carbon dioxide (sc-CO2) media were carried out. Using octene-1, styrene, and their derivatives as examples, the effectiveness of the developed method for obtaining valuable 1,2-functionalized products, including nitroalcohols, dinitroalkanes, and nitronitrates have been shown. Due to the application of sc-CO2, the proposed method compares favorably with known analogs by the absence of by-products and waste organic solvents, as well as lesser fire and explosion hazards.

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ACKNOWLEDGMENTS

This work was financially supported by Russian Science Foundation (project 20-73-00230).

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Authors and Affiliations

  1. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, Moscow, Russia

    R. E. Ivanov, M. N. Zharkov & S. G. Zlotin

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  1. R. E. Ivanov
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  2. M. N. Zharkov
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  3. S. G. Zlotin
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Corresponding author

Correspondence to M. N. Zharkov.

Additional information

The work is presented in the virtual issue “Young Scientists of the Russian Academy of Sciences.”

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Ivanov, R.E., Zharkov, M.N. & Zlotin, S.G. Nitration of Alkenes and Oxiranes with Nitrogen(IV) Oxide in Liquid and Supercritical Carbon Dioxide Media. Dokl Chem 500, 209–212 (2021). https://doi.org/10.1134/S0012500821100037

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