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The Electronic Structure of Transient Species in the Photochemical Reduction of Porphyrins

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Abstract

Studies on the electronic structure of π-radical anions and π-dianions of Zn porphyrins, Zn chlorins, π-anions of Zn phlorins, and porphodimethenes by electronic absorption spectroscopy, luminescence, picosecond spectroscopy, ESR, NMR, IR, and Raman spectroscopy are briefly surveyed. The experimental data are compared with the results of quantum-chemical calculations. The electronic structure of M-anions with an excess charge on the central ion of a transition metal (Fe, Ni, Co, and Pd) is discussed.

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Authors and Affiliations

  1. Institute of Molecular and Atomic Physics, National Academy of Sciences of Belarus, pr. F. Skoriny 70, Minsk, 220072, Belarus

    G. N. Sinyakov, A. M. Shul'ga & I. V. Filatov

  2. Czenstochowa Polytechnical Institute, al. Armii Krajowej 19, Czenstochowa, 42200, Poland

    K. Dzilinsky

Authors
  1. G. N. Sinyakov
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  2. A. M. Shul'ga
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  3. I. V. Filatov
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  4. K. Dzilinsky
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Sinyakov, G.N., Shul'ga, A.M., Filatov, I.V. et al. The Electronic Structure of Transient Species in the Photochemical Reduction of Porphyrins. High Energy Chemistry 36, 255–259 (2002). https://doi.org/10.1023/A:1016225407069

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