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Formation of a Dimer with a Double Hydroxo Bridge in Nitric Acid Solutions of the Nitrosotetranitrohydroxo Complex of Ruthenium(II). Crystal Structure of K2[RuNO(NO2)3(μ-OH)]2

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Abstract

Fine yellowish orange crystals of the binuclear complex K2[RuNO(NO2)3(μ-OH)]2 were obtained by the reaction of K2[RuNO(NO2)4OH] with a stoichiometric amount of 0.8 M nitric acid at room temperature. The compound was investigated by IR spectroscopy, X-ray phase analysis (DRON-3M, CuKα radiation), and X-ray diffraction analysis (Nonius CAD-4, MoKα radiation, graphite monochromator, ω scan mode, 1406 reflections). The crystals are poorly soluble in water and practically insoluble in ethanol and acetone; the compound is stable when stored in air. Crystal data for H2K2N8O16Ru2 are: a = 8.596(2), b = 10.111(1), c = 9.537(1) Å, β = 104.42(1)°, V = 802.8(2) Å3, space group \(P2_1 {\kern 1pt} /{\kern 1pt} c\), Z = 2, ρ calc = 2.691 g/cm3. The structure is built of [RuNO(NO2)3(μ-\(OH)]_2^{2 - } \) complex anions and K+ cations.

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    V. A. Emelyanov, S. A. Gromilov, I. A. Baidina, A. V. Virovets & A. V. Belyaev

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  1. V. A. Emelyanov
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  2. S. A. Gromilov
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  3. I. A. Baidina
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  4. A. V. Virovets
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  5. A. V. Belyaev
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Emelyanov, V.A., Gromilov, S.A., Baidina, I.A. et al. Formation of a Dimer with a Double Hydroxo Bridge in Nitric Acid Solutions of the Nitrosotetranitrohydroxo Complex of Ruthenium(II). Crystal Structure of K2[RuNO(NO2)3(μ-OH)]2. Journal of Structural Chemistry 43, 147–152 (2002). https://doi.org/10.1023/A:1016042404186

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